A sp(3)-sp(2) C-C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C-Br oxidative addition, and C-C reductive elimination in a model gold complex are shown. W...

Abstract The study investigates hydrogenation of CO 2 over mono- and bimetallic catalysts supported on biochar. In this reaction, iron–cobalt were shown to surpass monometallic iron cobalt in terms catalytic performance. optimal combination performance parameters was reached at an ratio 3 : 1. composition genesis the active phase Fe–Co catalyst identified, mechanism suggested for iron-dominated...

Six Co-Rh/Fe3O4 catalysts with different cobalt loadings were prepared by the co-precipitation of RhCl3, Co(NO3)2, and Fe(NO3)3 using Na2CO3 as the precipitant. These catalysts were tested for dicyclopentadiene (DCPD) hydroformylation to monoformyltricyclodecenes (MFTD) and diformyltricyclodecanes (DFTD). The results showed that the MFTD formation rate increased with increasing cobalt loading, ...

Abstract Nickel based nano-catalysts, supported on bimetallic oxide support (i.e. Ni/Al 2 O 3 -MgO) were prepared by the co-precipitation (one step, Catalyst-A) and followed impregnation (two steps, Catalyst-B) techniques separately. The catalysts then tested for dry reforming of methane (DRM) reaction. effect catalyst synthesis technique their performance has been analysed. -MgO nano-catalyst ...

Bimetallic Fe–Cu MOF was effectively synthesized through a one-pot solvothermal process and successfully characterized by TEM, XPS, SEM, XRD, BET, EDX, elemental mapping, FT-IR analysis. This bimetallic employed as catalyst in the reduction of nitroarenes at room temperature well dyes, for example, methyl orange (MO) methylene blue (MB). Results pointed to exhibiting outstanding catalytic perfo...

Bimetallic Ni-Cu/SiO2 catalysts with different Cu loading (2–5 wt%) were developed for liquid phase selective hydrogenation of furfural to furfuryl alcohol. Among these, bimetallic 2%Ni-X%Cu/SiO2 (X = 2, 5) exhibited better catalytic performances than monometallic 2%Ni/SiO2 and 2%Cu/SiO2. Moreover, the 2%Ni-5%Cu/SiO2 catalyst showed best performance 94% conversion 64% alcohol selectivity. The s...