a new sorbent composed of 3-aminopropyltriethoxy-silane-coated magnetic nanoparticles, functionalized with rhodium(iii) porphyrin complex was synthesized and characterized by elemental analysis, x-ray diffraction (xrd), transmission electron microscopy (tem), fourier transform infrared spectroscopy (ft-ir) and thermogravimetric analysis (tga). the effect of some co-existing anions present in aq...

Biomimetic engineering presents an insightful strategy to access fascinating biocomposites integrating biological, chemical, and material functions. Herein, a new self-propelled hydrogen-bonded enzymatic framework through biomimetic bottom-up is reported. The metal-free, mesoporous, photoactive organic (HOF) exoskeleton in situ grown around catalase (CAT), enzyme well known for its ability the ...

A catalyst and sorbent is disclosed which comprises pellets with an absorbent core and a protective shell with a catalyst in the shell. Such material is especially well suited for steam reforming of hydrocarbons to produce hydrogen since a reforming catalyst can be incorporated in the shell and a sorbent for the by-product carbon dioxide can be used for the core. It is also well suited for prod...

Consider how these problems could be solved by using a solid phase (such as a chromatographic sorbent) instead of the second liquid phase. There are still two distinct phases that can be readily segregated. Also, by proper selection of pH and type of solid phase sorbent, one could optimize the conditions to selectively partition the component(s) of interest on the solid phase. After removal of ...

The GC monitoring of green house gases is a challenging task because the concentration of organic species such as methane are relatively low (ppm to ppb) and their analysis requires some level of preconcentration. Since methane is highly volatile, it is not easily retained on conventional sorbents. In this paper we present multiwalled carbon nanotubes (MWNTs) as an effective sorbent for a micro...

The efficiency of one-step and multi-step protocols of DNA isolation from lysed sputum samples containing the Mycobacterium tuberculosis complex has been compared. DNA was isolated using spin-cartridges containing a special silica-based sorbent modified with fluoroplast and polyaniline, or using an automated isolation system. One-step isolation using the obtained sorbent has been shown to ensur...

A new sorbent has been developed by grafting Hexamethylenetetramine on a mesoporous molecular sieve (SBA-15) by wet impregnation method. This sorbent (Hexamine/SBA-15) has been characterized using N2 physisorption, X-ray diffraction (XRD) at low angles (2θ°) and FT-IR. To investigate the H2S removal capacity of this adsorbent from CH4-containing gas mixtures, the breakthrough tests have been pe...