Lithium borate glasses with fixed alkali content of 10 Mole % and different modifiers have been prepared. To compare the role of fly ash as a glass modifier the content of glass modifier PbO, Al2O3 have been kept same to 5 mole %. To investigate the structure FTIR and UV-VIS spectra of prepared samples have been taken. From optical data optical band gap and cutoff wavelength have been calculate...

Sedimentation velocity was measured in a Spinco ultracentrifuge’ operating at 165,000 X g. The hormone solutions (0.5 per cent) were prepared with borate buffer of pH 9.7 or saline at pH 9.1. Table I presents a typical run in a borate buffer; the sedimentation velocity constant was calculated by the procedure described by Svedberg and Pedersen (3). It may be noted that the individual values of ...

A homoleptic phosphine adduct of thallium(I) supported by a tris(phosphino)borate ligand has been isolated and structurally characterized.

A new actinide borate phosphate, U2[BO4][PO4], was synthesized in a Walker-type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single-crystal X-ray diffraction data collected at room temperature. U2[BO4][PO4] crystallizes in the monoclinic space group P21/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 8...

Pharmaceutical preparations usually contain preservatives and sweeteners. When parabens are used as preservatives and a polyol as a sweetener, a transesterification reaction may happen, yielding the transester polyol-paraben. The products formed in the transesterification reaction of methylparaben and sorbitol were analyzed by micellar electrokinetic chromatography and by HPLC. Up to six positi...

In this work, we report permanent reduction of Eu to Eu in sodium borate glasses by irradiation of near-infrared femtosecond laser. Glass composition of sodium borate was 85B2O3–15Na2O. The glasses were doped with 0.05, 0.1, and 0.5mol% Eu2O3. Absorption and fluorescence dynamics were studied to investigate valence state change of europium ions and the energy transfer between Eu and Eu ions. As...

Three different aniline derivatives, namely m- and p-aminobenzoic acids and m-amino benzenesulfonic acid, were sequestered in between layers of a borate-based coordination polymer, based on lead(II) tetrakis(imidazolyl)borate. The aniline derivatives pre-organized in the interlayer spacing of the coordination polymer, and the reactivity of these pre-organized anionic monomers in the crystalline...

Managing urban pests with “environmentally-friendly” compounds has gained importance in recent years with the global deregistration of persistent organochlorine insecticides. Boron compounds, especially boric acid, zinc borate, and disodium octaborate tetrahydrate, are considered excellent options for preserving lumber from insect attack as well as decay by fungi and bacteria. Remedial borate a...

By tuning the synthetic conditions, a 3D gallo-borate with high second-harmonic generation response was obtained.