نتایج جستجو برای: brønsted acidic ionic liquid
تعداد نتایج: 285773 فیلتر نتایج به سال:
Until very recently, the term Lewis acidic ionic liquids (ILs) was nearly synonymous with halometallate ILs, with a strong focus on chloroaluminate(III) systems. The first part of this review covers the historical context in which these were developed, speciation of a range of halometallate ionic liquids, attempts to quantify their Lewis acidity, and selected recent applications: in industrial ...
New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Brønsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in solvent extraction studies.
CL-20 is one of the well-known non-nuclear powerful energetic materials. TADB is an important intermediate in synthesis of CL-20. One of the significant steps in synthesis of CL-20 is application of palladium catalysis for debenzylation of TADB which has some disadvantages such as the high cost, need to special reactor and high cost and need to especial reactor, therefore scientists to find a...
A simple and environmentally benign procedure for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol with aromatic aldehyde in the presence of [Et3NH][HSO4] as an acidic ionic liquid catalyst under solvent-free conditions has been developed. The reaction work-up is very simple and the catalyst can be easily separated from the reaction mixture and reused s...
Abstract-A novel and efficient method has been developed for the synthesis of pyrano[3,2-c]quinoline-2,5-dione derivatives by the convenient ultrasound-mediated condensation of 4-hydroxyquinolin-2-one with Meldrum’s acid and aldehydes in the presence of a catalytic amount of [HMIm]HSO4 as a green, efficient and reusable acidic ionic liquid medium. The stability of the ionic liquid during the re...
4, 10- Dinitro-2, 6, 8, 12- tetraoxa-4, 10- diazaisowurtzitane (TEX) is well known as an efficient Insensitive high explosive. It was usually prepared via nitration of 1, 4- diformyl- 2, 3, 5, 6- tetrahydroxy piperazine reaction using a mixture of fuming nitricacid and concentrated sulfuric acid. However, these traditional liquid acids are toxic, corrosive and produce hazardous waste. In additi...
In this work, the ionic liquid triethylamine-bonded sulfonic acid {[Et3N–SO3H]Cl}, N,N-diethyl-N-sulfoethanammonium chloride was used as a green acidic homogeneous catalyst to synthesis of 3,4-dihydropyrimidin-2(1H)-ones and 3,4-dihydropyrimidin-2(1H)-thiones as two categories of heterocycles, from aldehyde, dicarbonyl compound and urea or thiourea throughout the one-pot three components cycloc...
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