The anodic stripping voltammetry at a carbon paste electrode modified with thiol terminated self-assembled monolayer on mesoporous silica (SH-SAMMS) provides a new sensor for simultaneous detection of lead (Pb2+) and mercury (Hg2+) in aqueous solutions. The overall analysis involved a two-step procedure: an accumulation step at open circuit, followed by medium exchange to a pure electrolyte sol...

The electrochemical properties of a modified carbon paste electrode with the synthesized compound of 2,2'-[1,7–heptanediylbis(nitrilomethylidene)]-bis(4-hydroxyphenol) (DHBH) and graphite nanoparticle (GN) were studied by cyclic voltammetry (CV), chronoamperometry and differential pulse voltammetry (DPV) methods. The proposed electrode shows excellent electrocatalytic activity towards the oxida...

In this work we report preparation TiO2 hollow spheres and its application as an electrochemical sensor. Therefore the novel carbon paste electrode modified with TiO2 hollow spheres (TOHS), multi-walled carbon nanotubes (MWCNTs) and poly-glutamic acid (PGA) film (PGA/TOHS/MWCNTs/CPE) was used for simultaneous determination of dopamine (DA) and piroxicam (PRX) in the presence of ascorbic acid (A...

The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...

the conducting polymer films have been widely applied in the field of electrochemistry owing to their goodstability, permselectivity, unique physical and chemical properties. a novel nano-au/poly (4-aminobenzoicacid) (paba) film modified carbon paste electrode was fabricated for sensitive detection of acetaminophenin this paper. the paba film and nano-au/paba film were characterized by scanning...

The present work is a short review of our recent studies on PhotoFuelCells, that is, photoelectrochemical cells which consume a fuel to produce electricity or hydrogen, and presents some unpublished data concerning both electricity and hydrogen production. PhotoFuelCells have been constructed using nanoparticulate titania photoanodes and various cathode electrodes bearing a few different types ...

We report the fabrication, characterisation (SEM, TEM, XPS and Raman spectroscopy) and electrochemical implementation of a graphene paste electrode. The paste electrodes utilised are constructed by simply mixing graphene with mineral oil (which acts as a binder) prior to loading the resultant paste into a piston-driven polymeric-tubing electrode-shell, where this electrode configuration allows ...

A simple approach based on cyclic voltammetry (CV) was developed for the simultaneous determination of dopamine (DA) and uric acid (UA) in the presence of ascorbic acid (AA) using a modified glassy carbon paste electrode (GCPE). In the present study, analytical parameters were optimized and electrochemical performance of modified electrode was investigated. The calibration curves were obtained ...

The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...