نتایج جستجو برای: coii complexes
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Abstract. Dharmayanthi AB, Subagyo VNO, Nugraha RTP, Rahmini, Rahmadi C, Darmawan, Sutrisno H. 2022. Genetic characteristics and strain types of the invasive fall armyworm Spodoptera frugiperda (J. E. Smith) (Lepidoptera: Noctuidae) in Indonesia. Biodiversitas 23: 3928-3935. The armyworm, is an pest tropical region western hemisphere, which globally distributed, including Therefore, this study ...
The performances of alumina-supported cobalt catalysts strongly depend on Co/alumina interactions, that are poorly understood. In the present work, ?-alumina surfaces used as models polycrystalline support, to unravel their orientation dependent behavior by GI-EXAFS. CoII/?-alumina interactions in dried state investigated, with a resolution parallel versus perpendicular deposit formation. DFT c...
Population genetic variation and demographic history in Danaus plexippus (L.), from Mexico were assessed based on analyses of mitochondrial cytochrome c oxidase subunit I (COI; 658 bp) and subunit II (COII; 503 bp) gene segments and 7 microsatellite loci. The sample of 133 individuals included both migratory monarchs, mainly from 4 overwintering sites within the Monarch Butterfly Biosphere Rese...
The solution chemistry and solid-state structures of the Co(II), Fe(II), and Ni(II) complexes of 7,13-bis(carbamoylmethyl)-1,4,10-trioxa-7,13-diazacyclopentadecane (L) are reported as members of a new class of paramagnetic chemical exchange saturation transfer (paraCEST) MRI contrast agents that contain transition metal ions. Crystallographic data show that nitrogen and oxygen donor atoms of th...
The genus Drosophila has played an essential role in many biological studies during the last 100 years but much controversy and many incompletely addressed issues still remain to be elucidated regarding the phylogeny of this genus. Because information on the Neotropical species contained in the subgenus Drosophila is particularly incomplete, with this taxonomic group being underrepresented in m...
lanthanide(iii) chloro complexes of 4[n-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (hmbaaps) (i) and 4[n-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (tmbaaps) (ii) with the general composition lncl3.2l (ln = la, pr, nd, sm, gd, tb, dy or ho; l = hmbaaps or tmbaaps) are reported. all the complexes were synthesized in ethanolic medium and refluxed the ...
Two isostructural 1D compounds {[M3(hpdc)2(H2O)6] 2H2O}n (M = Mn, Co; H3hpde = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field...
Two novel heterotrimetallic octa-[Cu2CoPbCl4(L)4]2 (1) and pentanuclear [Cu2CoCd2Cl6(L)4(HOMe)2] (2) complexes have been prepared in one-pot reactions of zerovalent copper with metal chlorides in a methanol (for 1) or acetonitrile (for 2) solution of 2-(dimethylamino)ethanol (HL) in open air. The crystal structures of both compounds consist of discrete centrosymmetric heterotrimetallic molecule...
Pulse dipolar electron paramagnetic resonance spectroscopy (PDS) is continuously furthering the understanding of chemical and biological assemblies through distance measurements in nanometer range. New paramagnets pulse sequences can provide structural insights not accessible other techniques. In pursuit alternative spin centers for PDS, we synthesized a low-spin CoII complex bearing nitroxide ...
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