Here we report the development of an aqueous, self-assembling system of oppositely charged colloids leading towards particle arrangements with controlled order. The colloidal system consists of two types of particles, each consisting of refractive index matched colloidal core-shell microgel particles, which are either negatively charged or amphoteric. By slowly decreasing the pH of our system b...

Manipulation of particles at the surface of a droplet can lead to the formation of structures with heterogeneous surfaces, including patchy colloidal capsules or patchy particles. Here, we study the assembly and rearrangement of microparticles confined at the surface of oil droplets. These processes are driven by electric-field-induced hydrodynamic flows and by 'electro-shaking' the colloidal p...

2014 By postulating an approximate analytic form for the force between two colloidal particles arising from the structure of the intervening solvent, the solvent structure contributions to the small angle scattering from colloidal dispersions are analysed within a perturbation theory based on the random phase approximation. The force between two colloidal particles due to the solvent structure ...

Long-range hydrodynamics between colloidal particles or fibers is modelled by the fluid particle model. Two methods are considered to impose the fluid boundary conditions at colloidal surfaces. In the first method radial and transverse friction forces between particle and solvent are applied such that the correct friction and torque follows for moving or rotating particles. The force coefficien...

Undoubtedly, the DLVO theory has been and it is still very useful for explaining the stability of colloidal dispersions. This theory was independently developed by Derjaguin and Landau [1] and by Verwey and Overbeek [2] in the forties. According to this theory, the total interaction potential (VT) between two colloidal particles is the sum of the repulsive electrostatic interaction energy (VE) ...

Coating hydrogel films or microspheres by an adsorbed colloidal shell is one synthesis method for forming colloidosomes. The colloidal shell allows control of the release rate of encapsulated materials, as well as selective transport. Previous studies found that the packing density of self-assembled, adsorbed colloidal monolayers is independent of the colloidal particle size. In this paper we d...

We used fracture-label to establish ultrastructural localization of glycoproteins in cross-fractured nuclei of duodenal columnar and exocrine pancreatic cells. Mannose residues were detected in cell nuclei by labeling freeze-fractured tissues with concanavalin A-horseradish peroxidase X colloidal gold (Con A-HRP X CG) or direct concanavalin A X colloidal gold (Con A X CG); fucose residues were ...

Evaporation-driven colloidal self-assembly is a promising family of routes to large-area, low-cost, if imperfect, photonic crystals. The simplest example occurs at the surface of a stagnant, evaporating colloidal suspension. For an evaporating colloidal suspension in which the interface falls faster than the particles sediment, particles will accumulate at the solvent-air interface. If neither ...

To elucidate important parameters for in vitro toxicity assessment of C(60) and C(70) fullerene colloidal particles, experiments were carried out in culture medium using pulsed field gradient nuclear magnetic resonance (PFG-NMR), asymmetrical flow field-flow fractionation (AFFFF), and dynamic light scattering (DLS) methods. First, the amounts of total and bulk bovine serum albumin (BSA) molecul...