Copper-β-amyloid 16 (Aβ16) complexes were investigated by electrospray ionization mass spectrometry (ESI-MS). Copper(i) and (ii) complexes were formed on-line in a microchip electrospray emitter by using a sacrificial copper electrode as the anode in positive ionization mode. In the presence of ascorbic acid in the peptide solution, the amount of Cu(i)-Aβ16 generated electrochemically was even ...

Copper-b-amyloid 16 (Ab16) complexes were investigated by electrospray ionization mass spectrometry (ESI-MS). Copper(I) and (II) complexes were formed on-line in a microchip electrospray emitter by using a sacrificial copper electrode as the anode in positive ionization mode. In the presence of ascorbic acid in the peptide solution, the amount of Cu(I)-Ab16 generated electrochemically was even ...

Combined electrochemical and hydrothermal assisted by microwave was used for the preparation of copper phthalocyanin blue (Cu Pc) nanoparticles with sizes ranging from 5 to 35 nm. Phthalic anhydride, urea and ammonium molybdate catalyst were dissolved in aqueous solution of 1 M NH4Cl containing a small amount of lauric acid as capping agent to suppress the flocculation of pigment. Electrodes we...

Thermal energy was shown to be efficiently converted into electrical power in a thermally regenerative ammonia-based battery (TRAB) using copper-based redox couples [Cu(NH3)4 /Cu and Cu(II)/Cu]. Ammonia addition to the anolyte (2 M ammonia in a copper-nitrate electrolyte) of a single TRAB cell produced a maximum power density of 115 1 W m 2 (based on projected area of a single copper mesh elect...

This study provides an electrocoagulation process for the removal of copper from water using mild steel and stainless steel as anode and cathode, respectively. The effect of different operating parameters and coexisting ions on the removal efficiency of copperwas investigated. The results showed that the optimum removal efficiency of 97.8% was achieved at a current density of 0.02 A/dm2 and a p...

The electrochemical migration (ECM) behavior of copper-clad laminate (PCB-Cu) and electroless nickel/immersion gold printed circuit boards (PCB-ENIG) under thin electrolyte layers of different thicknesses containing 0.1 M Na₂SO₄ was studied. Results showed that, under the bias voltage of 12 V, the reverse migration of ions occurred. For PCB-Cu, both copper dendrites and sulfate precipitates wer...

Hot reformate gas produced by reforming of heavy fuels, such as JP-8, must be desulfurized prior to its use in a solid oxide fuel cell (SOFC). This requires development of sorbent materials with high sulfur absorption efficiency and capacity at the SOFC operating temperature (650-800 C) to avoid heat exchanger penalties. Sorbent performance stability in cyclic operation of sulfidation and regen...

All-Solid-State Batteries In article number 2206762, Yijie Liu, David Mitlin, and co-workers report a stable anode-free all-solid-state battery (AF-ASSB) with sulfide-based solid-electrolyte (argyrodite Li6PS5Cl). The is achieved by tuning the wetting of lithium metal on “empty” copper current-collector. cover image, sprinting antelope represent cations rapidly diffusing through solid-state sul...