Zinc (II) complex, [Zn(25-MBTSC)2I2] (1), where (25-MBTSC = (E)-2-(2,5-dimethoxybenzaldehyde) thiosemicarbazone, has been synthesized from the reaction of ZnI2 with 25-MBTSC in methanol as solvent at 25 ºC. It was characterized by elemental analysis (CHN) and is confirmed by single-crystal X-ray diffraction analysis. The complex 1 crystallizes in a triclinic system, with space group P-ī, having...

Abstract Polaritons are quasi-particles that combine light with matter, enabling precise control of at deep subwavelength scales. The excitation and propagation polaritons closely linked to the structural symmetries host materials, resulting in symmetrical polariton high-symmetry materials. However, low-symmetry crystals, symmetry-broken exist, exhibiting enhanced directionality for nanoscale m...

At present, the determination of crystal structures from data that have been acquired from twinned crystals is routine; however, with the increasing number of crystal structures additional crystal lattice disorders are being discovered. Here, a previously undescribed partial rotational order-disorder that has been observed in crystals of stefin B is described. The diffraction images revealed no...

Noncentrosymmetric potassium dihydrogen phosphate (KH2PO4 or KDP) in the tetragonal crystal phase is arguably the most extensively studied nonlinear optical crystal in history. It has prolific applications ranging from simple laser pointers to laser inertial confinement fusion systems. Recently, type IV high-pressure KDP crystal sheets with a monoclinic crystal phase having centrosymmetric prop...

Reflectance spectra may show very different and interesting shapes. The most interesting may be connected to Evans holes. Model calculations to reproduce this effect were done applying model dielectric function functions. When a weak oscillator appears within the frequency region of a strong one (i.e. between its TO and LO frequencies), its LO-mode frequency shifts towards higher wavenumbers. A...

Quaternions are ordered quadruples of four numbers subject to specified rules of addition and multiplication, which can represent points in four-dimensional (4D) space and which form finite groups under multiplication isomorphic to polyhedral groups. Projection of the 8 quaternions of the dihedral group D2h, with only two-fold symmetry, into 3D space provides a basis for crystal lattices up to ...

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

Floquet time crystal, which breaks discrete time-translation symmetry, is an intriguing phenomenon in non-equilibrium systems. It crucial to understand the rigidity and robustness of crystal (DTC) phases a many-body system, finding precisely solvable model can pave way for understanding DTC phase. Here, we propose study spin chain by mapping it superconductor through Jordan-Wigner transformatio...