نتایج جستجو برای: cyclic voltammetric

تعداد نتایج: 100677  

2012
Sunil Kumar Nagaraju

The electrochemical behaviour of ebastine was studied at hanging mercury drop electrode using cyclic voltammetry and differential pulse voltammetry. The molecule shows a single, well defined reduction peak due to the reduction of carbonyl group. The voltammetric conditions were optimized with respect to maximum peak signals. The linearity between the peak signal and the concentration of ebastin...

Journal: :Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 2014
Tanmoy Saha Abhigyan Sengupta Partha Hazra Pinaki Talukdar

Pyranine as a new class of fluorescent chemosensor for the Cu(+) ion is reported. The probe is capable of discriminating ranges of cations from the Cu(+) ion, even in competing environment. The dye displayed a rapid fluorescence response (t1/2 = 1.66 min) towards the Cu(+) ion, and the micromolar detection limit enabled the detection of the ion in environmental samples. The observed stoichiomet...

2017
Ali Kamal Attia Nisreen Farouk Abo-Talib Marwa Hosny Tammam

Purpose: A new sensitive sensor was fabricated for the determination of ivabradine hydrochloride (IH) based on modification with multiwalled carbon nanotubes using sodium dodecyl sulfate as micellar medium to increase the sensitivity. Methods: The electrochemical behavior of IH was studied in Britton-Robinson buffer (pH: 2.0-11.0) using cyclic and differential pulse voltammetry. Results: The vo...

2009
N. W. Khun E. Liu

Nitrogen doped diamond-like carbon thin films with or without platinum and ruthenium incorporation (N-DLC or PtRuN-DLC) were deposited on highly conductive p-Si substrates by DC magnetron sputtering to study the effect of Pt and Ru doping on the voltammetric performance of the N-DLC films. The potential windows of these film electrodes were measured in different electrolytic solutions, such as ...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه رازی - دانشکده علوم 1391

we have two part in this thesis, at first: the interaction of native calf thymus dna (ct-dna) with two anthraquinones including quinizarin (1,4- dihydroxy anthraquinone) and danthron (1,8- dihydroxy anthraquinone) in a mixture of 0.04 m brittone-robinson buffer and 50% of ethanol were studied at physiological ph by uv-vis absorption, florescence, circular dichroism spectroscopic methods, viscos...

2012
Rajeev Jain Ramkishor Sharma

Granisetron showed one well-defined reduction peak at Hanging Mercury Drop Electrode (HMDE) in the potential range from -1.3 to -1.5 V due to reduction of C=N bond. Solid-phase extraction technique was employed for extraction of Granisetron from spiked human plasma. Granisetron showed peak current enhancement of 4.45% at square-wave voltammetry and 5.33% at cyclic voltammetry as compared with t...

Journal: :Journal of colloid and interface science 2004
Chang Ok Kim Sun-Young Hong Minju Kim Su-Moon Park Joon Won Park

The surface of indium-tin oxide (ITO) substrates was successfully modified with aziridine. Modification of the surface was achieved through facile ring-opening, and hyperbranching polymerization of the ring-strained heterocycle initiated from the reactive group on the surface. Amine density of the aziridine-modified ITO measured with UV-vis spectrophotometry is 10 amines/nm2. Cyclic voltammetri...

2011
P. LALITHA

Many quinolones, substituted quinolines and thiones are well known for their biological activity. The redox characteristics of such biological substances may provide valuable information about the redox behaviour in living systems. The present paper is aimed at carrying out a methodical cyclic voltammetric investigation of the peak potential values of 4-methyl/phenyl -3vinyl quinoline-2(1H) one...

Journal: :Nanoscale 2015
Jia Liang Yingchao Yang Jing Zhang Jingjie Wu Pei Dong Jiangtan Yuan Gengmin Zhang Jun Lou

In this communication, nickel diselenide (NiSe2) nanoparticles are synthesized by a facile and low-cost hydrothermal method. The synthesis method can be extended to other metal diselenides as well. The electrode made of NiSe2 exhibits superior electrocatalytic activity in the hydrogen evolution reaction (HER). A low Tafel slope of 31.1 mV per decade is achieved for NiSe2, which is comparable to...

Journal: :Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 2005
Giiltekin Gökce Zehra Durmuş Habibe Tezcan Esma Kiliç Hamza Yilmaz

Cyclic voltammetric (CV) and chronoamperometric (CA) behaviors of 1,3,5-triphenylformazan (TPF), 3-(p-nitrophenyl)-1,5-diphenylformazan (PNF) and 3-(m-nitrophenyl)-1,5-diphenylformazan (MNF) were studied in dimethyl sulfoxide medium. TPF was found to give a single sharp cathodic CV peak corresponding to a gain of one-electron per molecule. The diffusion coefficient and the number of electrons t...

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