a new, simple, rapid, and cheap method for determination of trace amounts of nitrite ion is reported.determination is based on reduction of bromate ion by nitrite ion, in the presence of murexide inacidic media. during reaction of bromate ion with nitrite ion, the reaction mixture is decolorized.the absorbance changes is then monitored spectrophotometricaly at 520 nm, at 25 °c. dynamicrange of ...

The potentials of the couples Mo(IV)--(Mo(V) and Mo(V)--Mo(VI) in nitrate reductase from Escherichia coli K12 were measured as + 180 mV and + 220 mV respectively at pH 7.14. The potentials associated with two other e.p.r. signals, believed to be due to iron--sulphur centres, were measured as + 50 mV and + 80 mV.

In the structure of the title compound, [Mo(C(19)H(20)N(2)O(2))O(2)], the Mo atom exhibits oxidation state +VI and is surrounded by two O atoms and the tetra-dentate Schiff base ligand 2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methyl-idyne)]diphenolate in a distorted octa-hedral configuration. An intra-molecular C-H⋯O hydrogen bond between a methyl-ene group and one O atom of the O=Mo(...

To the Editor: We read with interest a paper on phospholipid analysis in this journal (1) but deferred comment until the publication of our own paper on the subject, which we believe contains relevant material (2). Sandhu refers to the formation of a Prussian blue complex as the result of a reaction between phospholipids and a chromogenic reagent containing molybdenum. Clearly this cannot be so...

A sensitive and rapid liquid chromatography-tandem mass spectrometry (LC-MS/MS) method has been developed and validated for the determination of asperosaponin VI in beagle dog plasma using glycyrrhizic acid as the internal standard (IS). Plasma samples were simply pretreated with methanol for deproteinization. Chromatographic separation was performed on a Hedera ODS-2 column using mobile phase ...

Simultaneous extraction of the morpholino dithiocarbamate (MDTC) chelates of Cr(III) and Cr(VI) ion from aqueous samples was accomplished by applying fabric phase sorptive extraction (FPSE) using a cellulose fabric modified with a sol-gel/polytetrahydrofuran composite. Following extraction, the chelates were separated by HPLC on a reverse phase C18 column with acetonitrile:water (65:35; v/v) as...

the isolated fungi species of different kinds from chromium contaminated soil sites located in nagalkeni, chennai were used for reducing chromium(vi) in a tannery industry wastewater of nagalkeni, chennai.  the experiments were conducted to know biosorption potential of isolated fungi species for removing chromium(vi) in a tannery industry wastewater against the different ph, fungi biomass and ...

Trace measurements of the element chromium (Cr) are of interest in a wide range of applications and matrices. In the environment, Cr exists in two different oxidation states, the trivalent Cr(III) cation and hexavalent Cr(VI) anion. In mammals, Cr(III) is an essential element involved in the regulation of glucose; however, the element in its hexavalent form demonstrates mutagenic and carcinogen...

The present study was an attempt to explore the efficiency of indigenous bacterium isolated from the effluent of Electroplating Industry in transforming hexavalent chromium into trivalent chromium. The isolated bacterium was characterized on the basis of its morphological, biochemical and physiological properties as Salmonella sp.S4. Response Surface Methodology (RSM) based on a three-level thr...