The warming exothermic peaks (WEX) first described by Luyet and coworkers in solutions of ethylene glycol, glycerol, and polyvinylpyrrolidone(PVP) was interpreted on the basis of a devitrification phenomenon, in which rapid cooling converts normal water to amorphous ice, which devitrifies on warming to the state of normal Ice I. Our present studies of the WEX phenomenon in aqueous solutions of ...

A series of 11 new protic ionic liquids with fluorous anions (FPILs) have been identified and their self-assembled nanostructure, thermal phase transitions and physicochemical properties were investigated. To the best of our knowledge this is the first time that fluorocarbon domains have been reported in PILs. The FPILs were prepared from a range of hydrocarbon alkyl and heterocyclic amine cati...

A growing body of experimental work indicates that physical vapor deposition provides an effective route for preparation of stable glasses, whose properties correspond in some cases to those expected for glasses that have been aged for thousands of years. In this work, model binary glasses are prepared in a process inspired by physical vapor deposition, in which particles are sequentially added...

Experiments reported herein document heterogeneous crystal nucleation on bubbles in supercooled lithium disilicate melt. Crystalline lithium disilicate (Li2Si2O5) nucleated and grew on small bubbles (;1 mm) with a one-to-one correspondence between the number of bubbles and crystals (ranging from ,102 to ;105 bubbles/mm3). Crystals grew on large bubbles (.100 mm) only in samples fused in N2, sug...

The body-centered cubic (bcc) phase tends to preferentially nucleate during solidification of highly undercooled liquid droplets of binary alloy systems, including Fe–Co, Fe–Ni and Fe–Cr–Ni. We investigate a similar tendency during the partial devitrification of Co-rich amorphous precursors of composition (Co1 xFex)88Zr7B4Cu1 by identifying the structure and composition of the nanocrystalline g...

The response of amorphous steels to shock wave compression has been explored for the first time. Further, the effect of partial devitrification on the shock response of bulk metallic glasses is examined by conducting experiments on two iron-based in situ metallic glass matrix composites, containing varying amounts of crystalline precipitates, both with initial composition Fe49.7Cr17.7Mn1.9Mo7.4...

Glass-ceramics are polycrystalline materials of fine microstructure that are produced by the controlled crystallisation (devitrification) of a glass. Numerous silicate based wastes, such as coal combustion ash, slag from steel production, fly ash and filter dusts from waste incinerators, mud from metal hydrometallurgy, different types of sludge as well as glass cullet or mixtures of them have b...

Applications in security and electronic surveillance require a combination of excellent magnetic softness with good mechanical anticorrosive properties low dimensionality. We overviewed the feasibility using glass-coated microwires for article applications, as well different routes tuning individual or microwire arrays, making them quite attractive applications. provide hysteresis loops’ nonlin...

A new approach to thermal analysis is described that combines microscopy, a temperature controlled stage and image analysis. It is shown how images acquired using a hot stage microscope can be analysed by a robust algorithm that tracks how structures change as a sample is heated; we call this new method thermal analysis by structural characterisation or TASC. We present an overview of how it ca...