The new cis-dioxomolybdenum (VI) complexes [MoO2(L2)(H2O)] (2) and [MoO2(L3)(H2O)] (3) containing the tridentate hydrazone-based ligands (H2L2 = N'-(3,5-di-tert-butyl-2-hydroxybenzylidene)-4-methylbenzohydrazide H2L3 N'-(2-hydroxybenzylidene)-2-(hydroxyimino)propanehydrazide) have been synthesized characterized via IR, 1H 13C NMR spectroscopy, mass spectrometry, single crystal X-ray diffraction...

The photocatalytic process employing nanostructured semiconductor materials has attracted great attention in energy production, CO2 reduction, and water/air purification for decades. Recently, applying heterogeneous photocatalyst the synthesis of valuable chemicals is gradually emerging considered as a promising conversion cheap resources (i.e., biomass derivatives, polyols, aromatic hydrocarbo...

The development of efficient catalysts that include the advantages homogeneous and heterogeneous is a challenge can be achieved with metal-organic frameworks (MOFs) since they incorporate different functionalities in their structure make them promising for processes. Herein, two new isoreticular nitrogen-rich naphthalene cobalt-MOFs, Co-NDTz Co-NDPhTz, were successfully prepared under solvother...

Iron (III) meso-tetrakis(p-sulfonatophenyl)-β-octabromoporphyrin supported on Amberlite IRA- 400 [Fe(Br8 TPPS)-Ad-400] is a robust and efficient catalyst for oxidation of alkenes and alcohols at room temperature. The catalyst exhibits a high activity and stability in hydrocarbon oxidation by H2 O2 . The method was useful in the oxidation of various primary, secondary-aliphatic, alicyclic and ar...

   Mo-doped SnO2 nanoparticles were prepared using hydrothermal method. The average grain size obtained by varying calcinations temperature from 160 to 500 oC showed the different sizes. Prepared materials characterized by X-Ray diffraction (XRD) and scanning electron microscopy (SEM). Also the FTIR and the UV–Vis absorptive spectra have been carried out. Mo- doped SnO...

Most industrial enzymes are hydrolases, such as glycosidases and esterases. However, oxidoreductases have an unexploited potential for substituting harsh (and scarcely selective) chemical processes. A group of basidiomycetes are the only organisms degrading the aromatic lignin polymer, enabling the subsequent use of plant polysaccharides. Therefore, these fungi and their ligninolytic peroxidase...

Ti-MCM-41 was synthesized at pH 3, 7 and 11. The titanium content was determined by AAS and found to be 4%, 3.2% and 4.5%, respectively. In order to increase the titanium content in Ti-MCM-41, Ti(IV) ions were grafted onto Ti-MCM-41 using TiCl4 in toluene and Ti(OBu)4 in ethanol. The incorporation of Ti was determined to be 28% and 30%, respectively. The oxidation of olefins such as cyclopenten...