Miniature hollow fibre modules were fabricated as phase contactors for liquid-liquid extraction. They were tested for americium(III)-lanthanide separation, using 2,6-di(5,6-dipropyl-1,2,4-triazin3-yl)pyridine or a synergistic mixture of di(chlorophenyl)dithiophosphinic acid and tri-n-octyl phosphine oxide as extractants. Americium could be removed from the feed phase to 99.95% using the former ...

A macrocyclic trinuclear complex of (1,3,5-trimethylbenzene)ruthenium(II) bridged by 2,3-dioxopyridine was synthesized, and the extraction properties for lithium and sodium picrates were investigated in a dichloromethane/water system at 25 degrees C. The complex was found to have extremely high extractability and selectivity for lithium picrate; the logarithmic values of the extraction constant...

A modification of the semiautomated assay method of Antonis (1965. J. Lipid Res. 6:307-312) for free fatty acid is presented. Free fatty acids are extracted from serum or plasma into di-n-butyl ether-2-methoxyethanol; the extract is almost free from phospholipids. The acids are analyzed in a portion of extract by a copper soap method using diphenylcarbazide. The extractant, being less dense tha...

The methods used to facilitate the supercritical fluid extraction (SFE) of polar and ionic compounds are based on two general principles, either increasing the polarity of the supercritical fluid (SF) (usually CO,) used as extractant or reducing the polarity of the analytes to be leached from the solid matrices. Changes in the pressure and temperature of the SF, the use of SFs more polar than C...

In this paper, extractants are presented which made it possible to separate actinides(III) and lanthanides from strong nitric acid solutions (0.05 1 mol/L). For this purpose, new aromatic dithiophosphinic acids were synthesised and characterised, and the distribution ratios of Am(III), Eu(III) and all relevant lanthanides were determined in batch extraction experiments. The extractant used was ...

Tri-n-butyl phosphate (TBP) is an important extractant for heavy metal ions. The microscopic structure of TBP/n-octane mixtures as a function of concentration of TBP is examined through atomistic molecular dynamics simulations. A weak association between TBP molecules both in pure TBP as well as in the octane solution is established. In dilute TBP/n-octane solutions, TBP molecules are inhomogen...

A liquid membrane containing diethylene glycol monobutyl ether (2) shows specificity for K ion in transport while diethylene glycol dibutyl ether (1) was selective for Na over K . As an extractant, ligand 2 exhibited pronounced extraction selectivity for K over Na in comparison with ligand 1

The results of studying the physical properties a deep eutectic solvent based on choline chloride and sulfosalicylic acid have been presented. A phase diagram for this two-component mixture has constructed, dependences its density refractive index temperature studied first time. molar refractivity under study calculated. possibility using as an extractant recovery metal ions in solid–liquid sys...