An electro-Fe2+-activated peracetic acid (EC/Fe2+/PAA) process was established for organic dye removal in water. The operation factors such as the PAA dosage, Fe2+ amount, current density, and pH were investigated on methylene blue (MB) synergistic EC/Fe2+/PAA system. Efficient MB decolorization (98.97% 0.06992 min−1) achieved within 30 min under 5.4 mmol L−1 PAA, μmol Fe2+, 15 mA cm−2 intensit...

Despite its essentiality to life, iron presents significant challenges to cells: the exceedingly low solubility of Fe3+ limits its bioavailability, and the reactivity of Fe2+ toward H2O2 is a source of the toxic hydroxyl radical (HO•). Consequently, cellular levels of free iron are highly regulated to ensure sufficiency while preventing iron-induced toxicity. Relatively little is known about th...

The kinetics and mechanism of the reaction between iron() and sulfur() was studied at high iron() excess at 10.0 and 25.0 C in 1.0 M NaClO4 by the stopped-flow method. The number of absorbing species in this system was determined by matrix rank analysis of time-resolved spectra. The reaction exhibits composite kinetic features which could be explained by considering the reactions of Fe(...

As an advanced oxidative processes, the Fenton process is receiving popularity as a wastewater treatment technique that can be used for hazardous landfill leachate. The simple, yet involves complex interactions between affecting parameters including reaction time, H2O2/Fe2+ ratio, pH, and iron (II) ion concentration. Hence, purpose of this present study was to analyze factors leachate well thei...

Soil moisture status has an important effect on the process of denitrification in paddy soils. However, it is unclear how affects ferrous iron-involved denitrification. Here, influence drying-rewetting cycles soil were studied with batch experiments. The dynamics nitrate, ammonia, Fe2+, Fe3+ and total organic carbon (TOC), as well nitrous oxide (N2O) investigated using iron-rich Jiangxi provinc...

kinetics of radical polymerizations of waterborne alkyd/acrylic hybrid resin via batch mini-emulsion technique was studied using redox initiators (tbhp/fe2+/edta/asac  and  tbhp/fe2+/edta/sfs) at relatively low temperatures and thermal initiators (bpo, kps and aibn) at higher temperatures to seek the most suitable initiator system. at the end of all reactions the unreacted monomer content was r...

Ozonation is one of the most effective and efficient advanced oxidation processes (AOPs) has shown great potential in treatment industrial effluent wastewater. In present work, ozone-Fenton process for % COD color removal together with electrical energy per order (EE/O) determination distillery wastewater (DIW) was established. The developed by combining ozone (O3) Fenton (Fe2+/H2O2) process. (...

Department of Chemistry, Texas A & M Un E-mail: [email protected] Department of Chemistry, Tamkang Univer † Electronic supplementary informati spectroscopic, additional electrochemic crystallographic data (CIF) from the s [Ni2–Fe2] , [Ni2–Fe] , and computation crystallographic data for the complexes [ deposited in the Cambridge Crystallog (CCDC 1045461), [Ni2–Fe2] 2+ (CCDC 104 For ESI and ...

The combination of microbial reduction and further microbial oxidation of iron was applied to the treatment of food-processing wastewater and recovery of ammonium. Fe2+ ions were formed by ironreducing bacteria under anaerobic conditions. Ammonium was recovered by co-precipitation with negatively charged iron hydroxides produced during oxidation of Fe2+ by iron-oxidizing bacteria under microaer...