Background The recalcitrance of lignocellulosic biomass offers a series of challenges for biochemical processing into biofuels and bio-products. For the first time, we address these challenges with a biomimetic system via a mild yet rapid Fenton reaction and lignocellulose-degrading bacterial strain Cupriavidus basilensis B-8 (here after B-8) to pretreat the rice straw (RS) by mimicking the nat...

Vanadyl (VO2+) complexed to RNA reacts with hydrogen peroxide in a Fenton-like manner producing hydroxyl radicals (.OH). The hydroxyl radicals can be spin trapped with 5,5-dimethyl-1-pyrroline-1-oxide (DMPO) forming the DMPO-OH spin adduct. In addition, in the presence of ethanol the formation of the hydroxyethyl radical adduct of DMPO (DMPO-ETOH) confirms the production of hydroxyl radicals by...

The requirement of acidification for the successful Fenton processes in water treatment has promoted search new strategies to work at pH close neutrality. With this objective, use nZVI been evaluated oxidative elimination 10 mg L?1 atrazine circumneutral with nZVI/UVA, nZVI/H2O2, and nZVI/H2O2/UVA systems. While UVA irradiation sole was ineffective degrading herbicide, addition H2O2 boosted up ...

Among various advanced oxidation processes, coupled photocatalysis and heterogeneous Fenton-like catalysis (known as photo-Fenton-like catalysis) to generate highly reactive species for environmental remediation has attracted wide interests. As an emerging metal-free photocatalyst, graphitic carbon nitride (g-C3N4, CN) been recently recognized a promising candidate catalyze robustly reactions w...

Cu(II)-catalysed decomposition of hydrogen peroxide at alkaline pH in the presence of etidronic acid (HEDP) showed a sigmoid kinetic profile typical of autocatalytic reactions. However, the reaction abruptly stopped well before all hydrogen peroxide had decomposed, and further addition of Cu(II) and HEDP did not restart the reaction. Results of a mechanistic study suggest that the reaction invo...

Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10 wt%, associated with the beneficial intercalation of GO within Fe3O4 nanoparticles and resulting in higher...

Electro-Fenton reactions can be very effective for organic pollutant degradation, but they typically require non-sustainable electrical power to produce hydrogen peroxide. Two-chamber microbial fuel cells (MFCs) have been proposed for pollutant treatment using Fenton-based reactions, but these types of MFCs have low power densities and require expensive membranes. Here, more efficient dual reac...

Many types of advanced oxidation processes (AOPs), namely Fenton (Fe 2+ /H2O2) with different doses, Fenton-like (UV/Fe 2+ /H2O2), photo-Fenton (Fe 2+ /H2O2/TiO2), and plasma technology have been investigated for the removal of organic matters (COD content) from landfill leachate. Fenton's oxidation was the most effective as the most effective ratio 1/10 (Fe 2+ /H2O2) which allow the COD remova...