In this experiment you will be concerned with the decay kinetics of the fluorescence of quinine sulfate in water solutions and the physical processes that effect these. Quinine is used as a fluorescence standard because the fluorescence is not quenched (decreased) by oxygen but can be quenched in a controlled manner by adding atomic anions (F-, Cl-, Iand Br-) to the solution . Many molecules re...

Excitation-emission matrix spectroscopy (EEMS) was used to characterize the ultra violet fluorescence fingerprints of eight crude oils (with a 14,470-fold range of dynamic viscosity) in seawater. When the chemical dispersant Corexit 9500 was mixed with the oils prior to their dispersion in seawater, the fingerprints of each oil changed primarily as an increase in fluorescence over an emission b...

We present a preliminary analysis of the X-ray spectrum of the accretion disk corona source, 4U 1822−37, obtained with the High Energy Transmission Grating Spectrometer onboard the Chandra X-ray Observatory. We detect discrete emission lines from photoionized iron, silicon, magnesium, neon, and oxygen, as well as a bright iron fluorescence line. Phase-resolved spectroscopy suggests that the rec...

Metallic nanoparticles (NPs) are able to modify the excitation and emission rates (plasmonic enhancement) of fluorescent molecules in their close proximity. In this work, we measured the emission spectra of 20 nm Gold Nanoparticles (AuNPs) fixed on a glass surface submerged in a solution of different fluorophores using a spectral camera and 2-photon excitation. While on the glass surface, we ob...

A new class of heteroacenes containing B, N and S elements in the 22-electron aromatic nucleus has been synthesized by reaction of diaminoterthiophenes with dichlorophenylborane. Their structure was studied by X-ray crystallography and DFT calculations. UV-Vis absorption /emission spectroscopy shows high rigidity and deep-blue fluorescence of these compounds.

The synthesis, comprehensive linear photophysical characterization, two-photon absorption (2PA), steady-state and time-resolved stimulated emission depletion properties of a new fluorene derivative, (E)-1-(2-(di-p-tolylamino)-9,9-diethyl-9H-fluoren-7-yl)-3-(thiophen-2-yl)prop-2-en-1-one (1), are reported. The primary linear spectral properties, including excitation anisotropy, fluorescence life...

A combination of high performance size exclusion chromatography with organic carbon detector and ultraviolet detector coupled with peak-fitting technique and fluorescence excitation-emission matrix spectrometry applied fluorescence regional integration method was conducted to determine the characteristics of organic matter during nitrification. The batch scale of bionet nitrification without or...

this article presents the method of extraction-preconcentration of lead, cadmium, and nickel ions from food samples using the ghezeljeh montmorillonite nanoclay (geleh-sar-shoor) as a new native adsorbent in batch single component systems. the extraction-preconcentration of heavy metals were carried out by applying the solid phase extraction (spe) method followed by atomic absorption spectrosco...

Fluorescence spectroscopy with six wavelengths (369 nm, 395 nm, 400 nm, 405 nm, 410 nm, 416 nm) was performed to determine the optimal excitation wavelength of exogenously induced Protoporphyrin-IX fluorescence in esophageal adenocarcinoma cells and Barrett’s esophageal tissue, as this might improve (pre)malignant lesion identification in Barrett’s esophagus. Esophageal adenocarcinoma cell...