This paper considers the problem of transforming a resource feasible, fixed-times schedule into a partial order schedule (POS) to enhance its robustness and stability properties. Whereas a fixed-times schedule is brittle in the face of unpredictable execution dynamics and can quickly become invalidated, a POS retains temporal flexibility whenever problem constraints allow it and can often absor...

In this work, a novel soft shape memory polymer nanocomposite derived from a bacterial medium-chain-length polyhydroxyalkanoate, poly(3-hydroxyoctanoate-co-3-hydroxyundecenoate) (PHOU), used to form a covalent network grafted with polyhedral oligomeric silsesquioxane (POSS), a crystallizable inorganic–organic hybrid nanofiller, was prepared. The PHOU– POSS nanocomposite, PHOU–POSSw-net [w (1⁄4 ...

A new approach is presented for detecting whether a particular computation of an asynchronous distributed system satis es Poss (read \possibly "), meaning the system could have passed through a global state satisfying predicate , or Def (read \de nitely "), meaning the system de nitely passed through a global state satisfying . Detection can be done easily by straightforward state-space search;...

Incorporation of additives into a reinforced concrete matrix to delay or even completely avoid the initiation corrosion during service-life construction is widely pursued topic. One new promising technologies achieving increased interest incorporate inhibitors encapsulated in layered double hydroxide (LDH). LDH structures follow controlled release inhibitor while chloride efficiently trapped at...

An acid-base switchable dendritic complex was constructed by self-assembly between dibenzo-24-crown-8 terminated T(10)-POSS dendrimer and dibenzylammonium hexafluorophosphate salt based on T(8)-POSS. The formation and its threading-dethreading property were characterized by (1)H NMR and UV-visible absorption spectroscopy.

In situ endothelialization of cardiovascular implants has emerged in recent years as an attractive means of targeting the persistent problems of thrombosis and intimal hyperplasia. This study aimed to investigate the efficacy of immobilizing anti-CD34 antibodies onto a POSS-PCU nanocomposite polymer surface to sequester endothelial progenitor cells (EPCs) from human blood, and to characterize t...

With the continuous and expanding use of implantable biomaterials in a clinical setting, this study aims to elucidate the influence of sterilization techniques on the material surface and bulk properties of two polyurethane nanocomposite biomaterials. Both solid samples and porous membranes of nondegradable polyhedral oligomeric silsesquioxane poly(carbonate-urea) urethane (POSS-PCU) and a biod...

A POSS-PMMA copolymer has been synthesised by conventional free-radical polymerisation reaction. Uniform electrospun fibres from this copolymer showed a water contact angle as high as 165 degrees with a sliding angle as low as 6 degrees . For the first time, we found that the electrospun fibres had a bundled nanofibril secondary structure with an ordered POSS morphology on the fibre surface.

A new hybrid material consisting of a polyhedral oligomeric silsesquioxane (POSS) and carbon nanotube (CNT) was synthesized by a simple and versatile approach entailing click coupling between azide moiety-functionalized POSS and alkyne-functionalized multi-walled CNTs. This approach provides a simple and convenient route to efficiently functionalize a wide variety of nanoscale nanostructure mat...

A coarse-grained model has been developed for simulating the self-assembly of nonyl-tethered polyhedral oligomeric silsesquioxane (POSS) nanoparticles in solution. A mapping scheme for groups of atoms in the atomistic molecule onto beads in the coarse-grained model was established. The coarse-grained force field consists of solvent-mediated effective interaction potentials that were derived via...