The essential oils of wintergreen and birch are composed primarily methyl salicylate. Because this compound can easily be synthesized, frequently adulterated. By using Gas chromatography-combustion/pyrolysis-isotope ratio mass spectrometry (GC-C/P-IRMS) in conjunction with TC/EA-IRMS, GC-FID, GC-MS, 14C radiocarbon dating, criteria will established that used to distinguish authentic natural fro...