The image segmentation methods based on Markovian assumption consist in optimizing a Gibbs energy function which depends on the observation field and the segmented field. This energy function can be represented as a sum of potentials defined on cliques which are subsets of the grid of sites. The Potts model is the most commonly used to represent the segmented field. However, this model expresse...

We prove the convergence of phase-field approximations of the Gibbs–Thomson law. This establishes a relation between the first variation of the Van-der-Waals–Cahn–Hilliard energy and the first variation of the area functional. We allow for folding of diffuse interfaces in the limit and the occurrence of higher-multiplicities of the limit energy measures. We show that the multiplicity does not a...

1. The Physics of Information 2 2. Thermodynamics 4 2.1. The laws 5 2.2. Free energy 8 3. Statistical mechanics 9 3.1. Definitions and postulates 10 3.2. Counting microstates for a system of magnetic spins 11 3.3. The Maxwell-Boltzmann-Gibbs distribution 12 3.4. Free energy revisited 13 3.5. Gibbs entropy 13 4. Nonlinear dynamics 15 4.1. The ergodic hypothesis 16 4.2. Chaos and limits to predic...

Image segmentation methods based on Markovian assumption consist in optimizing a Gibbs energy function which depends on the observation field and the segmented field. This energy function can be represented as a sum of potentials defined on cliques which are subsets of the grid of sites. The Potts model is the most commonly used to represent the segmented field. However, this model only express...

Elastic matrix distortion around a growing inclusion of a new phase is analyzed and the associated contribution to the Gibbs free energy is considered. The constant-composition transformation from the parent to product phase is considered within the frame of Landau theory of phase transitions. The volume misfit between the inclusion and matrix is assumed to originate from the transformation vol...

For a class of systems obeying Euler's equation of motion the existence of a quantity to be named "proper mechanical energy" (PME) is shown which, together with internal energy, results in a quantity to be named "proper energy" (PE), which is conserved under conditions of time-dependent potentials. The appertaining formal structure for the continuum mechanics of such systems is the counterpart ...

Noyes [Noyes, R. M. (1981) Proc. Natl. Acad. Sci. USA 78, 7248-7249] has obtained a result for the Gibbs free energy per unit mass in a continuous flow stirred tank reactor, which states that the steady-state free energy increases monotonically with decreasing residence time for any stable stationary point. We show that his derivation is based on an erroneous stability criterion. We further inv...

The Gibbs free energy of mixing dissipated when fresh river water flows into the sea can be harnessed for sustainable power generation. Pressure retarded osmosis (PRO) is one of the methods proposed to generate power from natural salinity gradients. In this study, we carry out a thermodynamic and energy efficiency analysis of PRO work extraction. First, we present a reversible thermodynamic mod...