Ethylammonium Propionate with high polarity and ionic conductivity was synthesized andcharacterized with 1HNMR and IR. This ionic liquid which is prepared from readily available startingmaterial in high yield shows reasonably high at viscosity and heat stability up to 150 °C. This IonicLiquid is able to dissolve most of organic solvents due to the hydrogen interaction between IonicLiquid and th...

Biocatalysis with free enzymes may not be economically viable due to the complexity of their recovery in the reaction medium. With the objective of enabling the total activity recovery yield of biocatalyst and to improve the operational characteristics, have been applied enzyme immobilization techniques. The main interest in the enzyme immobilization is to obtain a catalyst whose activity and s...

BACKGROUND Drop drying is a key factor in a wide range of technical applications, including spotted microarrays. The applied nL liquid volume provides specific reaction conditions for the immobilization of probe molecules to a chemically modified surface. RESULTS We investigated the influence of nL and μL liquid drop volumes on the process of probe immobilization and compare the results obtai...

Aerogel and xerogel are formed via hydrolysis and polycondensation reactions of silica precursors, such as tetraethylorthosilicate (TEOS), always careful not to cause collapse, reduction in surface area and pore size. Several studies shown the use sol-gel entrapment possesses a number of desirable attributes, as the enzyme is physically entrapped in a rigid glass framework that permitted stabil...

in this work, the ionic liquid triethylamine-bonded sulfonic acid {[et3n–so3h]cl}, n,n-diethyl-n-sulfoethanammonium chloride was used as a green acidic homogeneous catalyst to synthesis of 3,4-dihydropyrimidin-2(1h)-ones and 3,4-dihydropyrimidin-2(1h)-thiones as two categories of heterocycles, from aldehyde, dicarbonyl compound and urea or thiourea throughout the one-pot three components cycloc...

      A highly sensitive electrochemicalimmunosensor was developed to detect hCG based on immobilization ofhCG-antibody (anti-hCG) onto robust nanocomposite containing Gr, Chit,1-methyl-3-octyl imidazolium tetra fluoro borate ionic liquid (IL)(Gr-IL-Chit). AuNPs were used to immobilize hCG antibody on the modifiedelectrode. The amine groups of the antibody are cova...

In this study, a novel acidic magnetic dicationic ionic liquid was prepared in three steps to serve as a green  catalyst  in  organic  synthesis.  The  newly  synthesized  catalyst  was  characterized UV- VIS,  and  VSM  analysis.  Additionally,  the  decomposition  steps  acatalyst  were investigated by thermal  analysis  techniques  (TGA/DSC).  The  synthesized  acidic magnetic dication...

In this study, we present a new concept in chemically stabilized ionic liquid membranes: an ionic liquid organosilica (ILOS) membrane, which is an organosilica membrane with ionic liquid-like properties. A silylated ionic liquid was used as a precursor for synthesis. The permselectivity, permeation mechanism, and stability of the membrane in the H₂/toluene binary system were then compared with ...

an atom-efficient, eco-friendly, solvent-free, high yielding, multicomponent green strategy to synthesize triazolo[1,2-a]indazole-triones derivatives by the one-pot condensation of aldehyde, dimedone, and phenyl urazole is presented. a series of different substituted aromatic aldehydes including either electron-withdrawing or electron-donating groups used in this reaction participated well and ...

the magnetically recoverable fe3o4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (fe3o4-il-hso4) were synthesized and used as efficient magnetic catalysts for the regioselective thiocyanation of aromatic and heteroaromatic compounds at room temperature in water: ethanol. this procedure provided the target thiocyanat...