in situ atom transfer radical polymerization

Stackable gels comprised of layers of dissimilar polymers were synthesized by combining conventional free radical polymerization (FRP) and atom transfer radical polymerization (ATRP) using two approaches: (i) polymerization of a pre-gel solution containing a monomer and cross-linker introduced on top of a previously prepared gel, and (ii) simultaneous polymerization of two immiscible pre-gel so...

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preparation of high performance pp/ reduced graphene oxide nanocomposites through a combined in situ polymerization and masterbatch method

Journal: :polyolefins journal 0

he-xin zhang department of polymer science and engineering, kyungpook national university, korea seung-ri lee department of polymer science and engineering, kyungpook national university, korea dong-ho lee department of polymer science and engineering, kyungpook national university, korea xue-quan zhang key lab. of synthetic rubber, changchun institute of applied chemistry, chinese academic of science, china keun-byoung yoon department of polymer science and engineering, kyungpook national university, korea

despite the great potential of graphene as a nanofiller, achieving homogeneous dispersion remains the key challenge for effectively reinforcing polyolefin (such as polyethylene (pe) and polypropylene (pp)) nanocomposites. therefore, in this research, we report a facile combined in situ polymerization and masterbatch method for fabricating pp/reduced graphene oxide (rgo) nanocomposites. in the p...

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Controlled/"Living" Radical Polymerization. Halogen Atom Transfer Radical Polymerization Promoted by a Cu(I)/Cu(II) Redox Process

Journal: :Macromolecules 1995

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"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.

Journal: :Chemical reviews 2007

Nicolay V Tsarevsky Krzysztof Matyjaszewski

Chemical Reviews is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 “Green” Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials Nicolay V. Tsarevsky, and Krzysztof Matyjaszewski Chem. Rev., 2007, 107 (6), 2270-2299• DOI: 10.1021/cr050947p • Publication Date (Web): 27 Ma...

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Controlled fabrication of cross-linked nanoparticles/polymer composite thin films through the combined use of surface-initiated atom transfer radical polymerization and gas/solid reaction.

Journal: :Journal of the American Chemical Society 2002

Jia-Yu Wang Wei Chen An-Hua Liu Guang Lu Gang Zhang Jun-Hu Zhang Bai Yang

A promising strategy for the controlled synthesis of inorganic/polymeric nanocomposites may be sustained by fabricating cross-linked PbS nanoparticles/polymer composite thin films through combining surface-initiated atom transfer radical polymerization (ATRP) and gas/solid reaction. The introduction of Pb ions through the extension of surface-initiated ATRP to the monomers containing metal ions...

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