Mid-infrared laser ablation of water-rich targets at the maximum of the 2.94 mm absorption band is a two-step process initiated by phase explosion followed by recoil pressure induced material ejection. Particulates and/or droplets ejected by this high temperature high pressure process can be ionized for mass spectrometry by charged droplets from an electrospray. In order to gauge the internal e...

We investigate the coherent control of nonresonant two-photon excitation and (2 + 1) photon ionization processes from the time-dependent perspective. To this end, we have solved the time-dependent Schrödinger equation for a hydrogen atom interacting with an ultraviolet laser field. Results are obtained for symmetric and antisymmetric phase distributions leading to dark and bright pulses, for wh...

A novel analytical method, called Liquid Phase Ion Mobility Spectrometry (LiPIMS) was demonstrated, where aqueous phase analytes were ionized and introduced into non-aqueous liquids, transported by an external electric field from the point of generation to a collection electrode. Ions were produced from a unique liquid phase ionization process, called Electrodispersion Ionization. Spectra of an...

We study the wavelength scaling of high harmonic generation efficiency with visible driver wavelengths in the transition between the tunneling and the multiphoton ionization regimes where the Keldysh parameter is around unity. Our experiment shows a less dramatic wavelength scaling of efficiency than the conventional case for near- and mid-IR driver wavelengths, and it is well explained by a ge...

Recently performed experiments 1 have demonstrated that half-cycle pulses (HCPs), i.e. unimodular electromagnetic pulses, are a useful new spectroscopic tool which is particularly well suited for investigating the dynamics of weakly bound Rydberg electrons. Typically their pulse durations range from the subpicosecond to the nanosecond regime and these pulses have already been produced with elec...

time-dependent schrödinger equation for a 1-d model of hydrogen molecular ion h2+ in intenselaser field linearly polarized along the molecular axis is solved. ionization rates are calculated for differentinitial states. the evolution of electronic wavefunction at fixed inter-nuclear separations are simulated andanalyzed. the results obtained for the ground state of this 1-d model of h2+ show ap...

The objective of this work is to interpret inductive results obtained by the unsupervised learning method OSHAM. We briefly introduce the learning process of OSHAM, that extracts concept hierarchies from unlabelled data, based on a representation combining the classical, prototype and exemplar views on concepts. The interpretive process is considered as an intrinsic part in OSHAM and is carried...

We present a new and comprehensive approach to inductive databases in the relational model. The main contribution is a new inductive query language extending SQL, with the goal of supporting the whole knowledge discovery process, from pre-processing via data mining to post-processing. A prototype system supporting the query language was developed in the SINDBAD (structured inductive database de...

The structures of the four lowest alanine conformers, along with their radical cations and the effect of ionization on the intramolecular proton transfer process, are studied using the density functional theory and MP2 method. The energy order of the radical cations of alanine differs from that of the corresponding neutral conformers due to changes in the basicity of the NH2 group upon ionizati...

he main objective of the advertising discourse is to encourage its viewer or reader to buy goods. this dialogue contains several inductive functions, including inductive functions of action and tension. the function of the induced action is an action-induced origin, whereas the function of the inductive tension is induced by the action originated. thus, tension-induced functions can be claimed ...