The characterization and catalytic performance of Zn/ZSM-5 Zn-B/ZSM-5 catalysts in the n-hexane aromatization was reported. Catalysts were prepared by post-synthesis ion exchange thoroughly characterized means XRD, Py-FTIR, N2 adsorption, 27Al 11B MAS NMR spectroscopy electron microscopy techniques. incorporation zinc reduces Brønsted acid site density increases Lewis acidic sites final ZSM-5 b...

A most effective and less energy demanding method of producing fatty esters, diol esters, by esterifying fatty acids, with neopentyl and ethylenglycol alcohols in the presence of an acidic ion exchange resin catalyst(polyestyrendivinylbenzensulfated) was investigated at elevated temperature. In this process an azeotroping agent, toluene, was used to facilitate continuous removal of water by dis...

In this study, polystyrene ethylene butylene polystyrene (PSEBS) was functionalized to prepare mono and bipolar ion exchange membranes. In the case of the bipolar membrane, platinum was used as the intermediate layer. NaCl solution of concentration ranging from 5 g/L to 25 g/L was used as the feed solution. A commercially procured ion exchange membrane made of polystyrene divinyl benzene was al...

The authors experimentally demonstrate a simple and efficient approach for nucleating the catalytic chemical vapor deposition CVD growth of GaN nanowires, Ga2O3 nanowires, and Ga2O3 nanoribbons by using ion implantation of Fe+ into thermally grown SiO2 layers and subsequent annealing to form the catalyst nanoparticles. This work shows that ion implantation can be used as a versatile method to c...

Catalytic biomass conversion is often hindered by coking. Carbon compounds cover active surface and plug pores, causing catalyst deactivation. Material design at the nanoscale allows tailoring of the catalytic activity and stability. Here, we report a simple synthesis of nanosized ZSM-5 materials by using a silicalite-1 seeding suspension. ZSM-5 crystals were grown from a deionized silica sourc...

In this study, the preparations of biodiesel from three different feedstocks, including rapeseed oil, high acidified Chinese wood oil and trap grease, were carried out in a pilot scale of 200 t yr-1 biodiesel production system. The optimum operating conditions for transesterification of rapeseed oil in plug flow reactor were found to be as follows: the catalyst dosage is 1.2 wt%; the retention ...

In present research work, homogeneous anion exchange membranes based on polysulfone (QAPSFs) were prepared via chloromethylation, amination and alkalization. In amination step, trimethylamine and N,N,N',N'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. The chloromethylated polysulfone was characterized by 1HNMR spectroscopy and chloromethylation degr...

The development of a low-cost, high-performance platinum-group-metal-free hydroxide exchange membrane fuel cell is hindered by the lack of a hydrogen oxidation reaction catalyst at the anode. Here we report that a composite catalyst, nickel nanoparticles supported on nitrogen-doped carbon nanotubes, has hydrogen oxidation activity similar to platinum-group metals in alkaline electrolyte. Althou...