Solid electrolytes used in all-solid-state batteries electronically separate the positive and negative electrodes battery only allow carrier ions to pass through. KTiOPO 4 (KTP), a potassium ion-conducting solid electrolyte, was first applied as inner contact layer of an ion-selective electrode (ISE) stabilize membrane potential. Application KTP improved long-term potential stability ISE by sta...

a new polyvinyl choloride (pvc) membrane sensor for cerium (iii) was prepared based on 4,13-didecyl-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane (kryptofix22dd) as an ionophore. the sensor exhibites a linear concentration range of 1.0×10-6to 1.0×10-1m, with a nernstian slope of 18.0±1.0 mv/decade, and a detection limit of 9.7×10-7m. it has a fast response time (5 s) and can be used for two mont...

We present a systematic, multiscale, fully detailed numerical modeling for dynamics of fluid flow and ion transport covering Ohmic, limiting, and overlimiting current regimes in conductance of ion-selective membrane. By numerically solving the Poisson-Nernst-Planck-Navier-Stokes equations, it is demonstrated that the electroconvective instability, arising from the electric field acting upon the...

The pH-sensitive chromoionophores brought the dream of the ion-selective membrane scientist close to realization. With the help of these molecules, one can build pH-sensitive, ion-selective electrodes and look into the bulk of solvent polymeric membranes during potentiometric measurements (spectropotentiometry) and image concentration profiles in situ with high spatial and temporal resolution. ...

The recent introduction of miniature liquid ion-exchanger electrodes provides the possibility of overcoming previously encountered limitations on the measurement of specific ionic activities in biological fluids. Hydrogen ion and sodium ion activities have been stuccessfully determined by means of glass-membrane electrodes(l-5). However, in the presence of sodium, glass electrodes are usually i...