The effect of Mw on the non-isothermal crystallization kinetics of metallocene linear polyethylene (m-PE) was studied using modulated differential scanning calorimetry. Six linear m-PEs of molecular weights in the range 122-934 kg/mol were prepared by gas phase polymerization. The cooling rate was varied in the range 2–20C/min and it has significantly affected the crystallization behavior. The ...

In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal dehydrochlorination of two different samples of PVC. It has been observed that this dehydrochlorination is complex and involves two different processes. A model that accounts for the entire dehydrochlorination is proposed. This model involves nucleation and growth and diff...

Abstract Casting powders or mold fluxes, as they are more commonly known, used in the continuous casting of steel to prevent shell from sticking copper mold. The first melt and create a pool liquid flux above mold, then fluxes penetrate into gap between water-cooled shell, where crystallization solid phases takes place temperatures gradually drop. It is important understand behavior these becau...

The main objective of the present study was to develop and validate a new alternative modelling method predict shelf-life food products under non-isothermal storage conditions. bacterial growth data Pseudomonas spp. extracted from published studies conducted for aerobically-stored fish, pork chicken meat described with two-step one-step approaches employing different primary models (the modifie...

Nucleic acid secondary structure plays an important role in nucleic acid-nucleic acid recognition/hybridization processes, and is also a vital consideration in DNA nanotechnology. Although the influence of stable secondary structures on hybridization kinetics has been characterized, unstable secondary structures, which show positive ΔG° with self-folding, can also form, and their effects have n...

in the present study, different activated carbons were prepared from carbonized african beech wood sawdust by potassium hydroxide activation. the activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. the phenol adsorption capacity of the prepared carbons was evaluated. the different ...

In order to improve the traditional freezing crystallization process of calcium nitrate in nitric phosphate process, crystal growth experiments by adding Ca(NO3)2·4H2O seeds in supersaturated calcium nitrate solution in a Circulating Fluidized Bed (CFB) crystallizer were carried out on crystal growth kinetics. The results showed that the growth of C...

Controlled release tablets containing 50 mg diclofenac sodium (DS) and 40% mastic with other natural additives were prepared. Drug release was examined and stability was studied using non-isothermal and isothermal thermogravimetric analysis (TGA). The bioavailability of two controlled release tablet formulations was studied and compared to that of commercial tablets, and rabbit stomachs were al...

Isothermal kinetics of the exchange absorbed water in a silica hydrogel (SH) with ethanol was examined. The isothermal kinetic curves were measured at temperatures: T = 297, 306 and 316 K. rate analysed as function time. possibility mathematical description by Brouers Sotolongo-Costa?s (BS) fractal?s model Parameter values (n, ?, ?) their changes temperature calculated. By applying method Ozao,...