نتایج جستجو برای: lactide
تعداد نتایج: 3090 فیلتر نتایج به سال:
This article reviews various initiator used to synthesize high molecular weight (MW >10,000 g/mol) of polylactic acid (PLA) through ring-opening polymerisation (ROP) lactide. ROP has been chosen as the best method in producing PLA. On other hand, stannous octoate (Sn(Oct)2) reported catalyst for method. Many researchers have studied that rate with presence only Sn(Oct)2 is slow compared lact...
Amide and alkoxide coordination complexes of calcium supported by beta-diiminato and bulky trispyrazolylborate complexes are reported together with their activity in lactide ring-opening polymerization; some are amongst the most active systems discovered to date.
In this communication we report, for the first time, the ring-opening polymerisation in the melt of rac-lactide with heterogeneous catalysts. Homogeneous model systems based on silsesquioxanes have been prepared for comparison.
In this work, biodegradable Poly(L-lactide) (PLLA) was modified through adding a new organic additive N, N -bis(benzoyl) 1, 4-naphthalenedicarboxylic acid dihydrazide (NABH). A comparison on crystallization of the pure PLLA and PLLA/NABH revealed that NABH as effective heterogeneous nucleation sites enhanced PLLA
Characteristic poly(l-lactide) absorption peaks were identified at 1.8, 4.0, 4.7, and 7.1 THz for an 80 °C crystallization temperature (Tc) sample; higher Tc resulted in a blue shift of the peak frequency.
Abstract In the field of bioplastics, complete kinetic models are rare but needed for industrial scale‐up. Herein, a model is developed to describe behavior robust and nontoxic guanidine carboxy Zn complexes in lab‐scale ring opening polymerization (ROP) l ‐lactide, mimicking melt presence co‐initiator. The includes inter‐ intramolecular transesterification random chain scission, considering si...
Bicalutamide is the most widely used non-steroidal antiandrogen for treating early stage prostate cancer, but suffers variable oral absorption due to its limited aqueous solubility. Thus, our objective was to synthesize novel biodegradable copolymers for the systemic micellar delivery of bicalutamide. Flory-Huggins interaction parameter (cFH) was used to assess compatibility between bicalutamid...
The purpose of this study was to compare: a new five-layered poly (L-lactide-co-caprolactone) (PLC) membrane and small intestinal submucosa (SIS) as a control in rat urinary bladder wall regeneration. The five-layered poly (L-lactide-co-caprolactone) membrane was prepared by an electrospinning process. Adipose tissue was harvested from five 8-week old male Wistar rats. Adipose derived stem cell...
Linear aliphatic polyesters are degradable thermoplastic polymers, which can be obtained by ring-opening polymerization (ROP) of cyclic esters through a coordination-insertion mechanism. Aluminum based organometallic complexes have a leading position as efficient catalysts for this polymerization process. Aluminumalkyl complexes bearing salicylaldiminato ligands, although less explored, have be...
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