The linear 1-alcohols n-C(16)H(33)OH, n-C(17)H(35)OH, n-C(19)H(39)OH have been imbibed and solidified in lined up, tubular mesopores of silicon with 10 and 15 nm mean diameters, respectively. X-ray diffraction measurements reveal a set of six discrete orientation states ("domains") characterized by a perpendicular alignment of the molecules with respect to the long axis of the pores and by a fo...

This paper is a survey of our recently published and new results on nonlinear-optical studies of photonic band-gap (PBG) structures formed from mesoporous silicon. The studies are performed on photonic crystals, high-quality-factor microcavities (MC) with a half-wavelength-thick microcavity spacer, and on series of coupled microcavities with two identical microcavity spacers and controllable co...

3D mesoporous graphene (mesoG) was synthesized from [Ni2(EDTA)] (EDTA = ethylenediaminetetraacetate). The material is comprised of interconnected 4 nm-sized hollow carbon shells composed of 3-4 layers of graphene and exhibits high bifunctional electrocatalytic activity as well as high durability for use in oxygen evolution and reduction reactions.

In the frame of this work, the aim was to create a superparamagnetic nanocomposite system with a maximized magnetic moment when magnetized by an external field and a blocking temperature far below room temperature. For this purpose, iron oxide nanoparticles of 3.8-, 5- and 8-nm size have been infiltrated into the pores of porous silicon. To fabricate tailored magnetic properties of the system, ...

Silicon nanowires (SiNWs) are electrochemically porosified to generate mesopores in sizes of 2-50 nm, resulting in the creation of mesoporous silicon nanowires (mpSiNWs). The porosification imposes two characteristics on to SiNWs: an increase of surface areas in the porous profile and quantum confinement ascribed to the shrinkage of silicon skeletons. Since the first report on producing mpSiNWs...

The fluorescent dye Alexa Fluor 488 or the anticancer drug doxorubicin is attached to the surface and inner pore walls of mesoporous Si particles by covalent attachment, and the oxidation-induced release of each molecule is studied. The molecules are bound to the Si matrix using a 10-undecenoic acid linker, which is attached by thermal hydrosilylation. Loading capacity of the microparticles usi...

This work reviews the use of porous silicon (PS) as a nanomaterial which is extensively investigated and utilized for various applications, e.g., in the fields of optics, sensor technology and biomedicine. Furthermore the combination of PS with one or more materials which are also nanostructured due to their deposition within the porous matrix is discussed. Such nanocompounds offer a broad aven...