The hydrogen adsorption sites in MOF5 were determined using neutron powder diffraction along with first-principles calculations. The metal-oxide cluster is primarily responsible for the adsorption while the organic linker plays only a secondary role. Equally important, at low temperatures and high-concentration, molecules form unique interlinked high-symmetry nanoclusters with intermolecular di...

Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M3pz3-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The ~230 Å(3) cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M6-cyclohexane and Ag6-S8 host-guest species have been determined.

Drug delivery clusters based on nanocages recently have been the most capable to study. Adipic acid (ADPA) interaction mechanism over of X(Al/B)12Y(N/P)12 was investigated. We analyzed various electronic, chemical, and spectroscopic properties with adsorbed ADPA molecule. Adsorption energies were calculated study adsorption nanocages. Raman enhanced surface scattering is used track drug as an e...