We report a novel synthesis of Ti5Si3 nanoparticles (NPs) via the magnesio-reduction of TiO2 NPs and SiO2 in eutectic LiCl-KCl molten salts at 700 °C. The Ti5Si3 particle size (∼25 nm) is confined to the nanoscale due to the partial dissolution of Mg and silica in the molten salts and a subsequent heterogeneous reduction on the surface of the TiO2 NPs.

recently, the demands for the production of many different types of plastic wastes are greatly growing that subsequently, lead to the serious challenges in environmental considerations. since, these materials are rarely resolved by microorganisms, hence, their recycling to the useful materials is crucial. in the present study, we used a solution electrospinning technique to synthesize nano/micr...

this paper discusses about preparation of biodegradable polymer /clay nanocomposites based on organically modified montmorillonite clay; i.e. cloisite 10a and biodegradable polymer chitosan by solution mixing technique and their characterization. the nanocomposites were successfully prepared and their structures were characterized by powder x-ray diffraction (xrd), particle size analyzer (beckm...

Molten globules are partially folded states of proteins which are generally believed to mimic structures formed during the folding process. In order to determine the minimal requirements for the formation of a molten globule state, we have prepared a set of peptide models of the molten globule state of human alpha-lactalbumin (alphaLA). A peptide consisting of residues 1-38 crosslinked, via the...

Polymers are known to exhibit various flow instabilities during extrusion in which a molten polymer is forced to flow through a narrow die, in order to form a strand or acquire a desired shape of the final product. Recent developments in experimental techniques revealed that some of the instabilities are interfacial in nature, that is originate from the violation of the no-slip boundary conditi...

The hybrid molten/solid In2O3 - 30-48 wt.% Bi2O3 oxide materials were studied with respect to their transport properties. The conductivities, oxygen ion transport numbers and oxygen permeation fluxes have been measured by using the four-probe DC, volumetric measurements of the faradaic efficiency and gas flow techniques, respectively. We show that the...

CaZrO3 nanoceramics were successfully synthesized at 700 C using the molten salt method, and the effects of processing parameters, such as temperature, holding time, and amount of salt on the crystallization of CaZrO3 were investigated. CaCl2, Na2CO3, and nano-ZrO2 were used as starting materials. On heating, CaCl2–NaCl molten eutectic salt provided a liquid medium for the reaction of CaCO3 an...

Previous NMR studies have shown that many phospholipase A2 (PLA2, from bovine pancreas, overexpressed in Escherichia coli) mutants display some properties reminiscent of a molten globule state. Further NMR analyses for some of the mutants indicated that formation of the "molten globule-like state" is a pH-dependent phenomenon. The mutants I9Y and I9F showed perturbed NMR properties throughout t...