A very simple, ultra-sensitive and highly selective non-extractive spectrophotometric method for the determination of trace amount of molybdenum(VI) using 5,7-dibromo-8-hydroxyquinoline (DBHQ) has been developed. 5,7-Dibromo-8-hydroxyquinoline reacts in a slightly acidic solution (0.05 - 1.0 M H2SO4) with molybdenum(VI) to give a deep greenish-yellow chelate which has an absorption maximum at 4...

We study the selective catalytic oxidation of ethanol with air as a sustainable alternative route to acetaldehyde. The reaction is catalysed by molybdenum oxide supported on titania, in a flow reactor under ambient pressure. High selectivity to acetaldehyde (70%-89%, depending on the Mo loading) is obtained at 150 °C. Subsequently, we investigate the structure/performance relationship for vario...

Abstract The caesiated surface negative ion (H - ) source is the first element of CERN's LINAC4 a linear injector designed to accelerate hydrogen ions 160 MeV. IS03 operated at 35 mA beam intensity and reliably feeds accelerator chain, H are generated via plasma volume molybdenum (Cs-Mo) electrode mechanisms. Studying extraction region this essential for optimizing production. 3D Particle-in-ce...

In this study, molybdenum-copper/alumina nano composite was synthesized with mechano-chemical method using high energy planetary ball milling. The molybdenum oxide, copper oxide and aluminum powder were used as starting materials and reaction appeared to occur through a rapid combustion reaction process. The evaluation of powder particles after different milling times was studied by X-ray diffr...

   Nickel-molybdenum oxidebimetallic nanoparticles were synthesized in ethylene glycol using the microwave irradiation technique. According to the results, successive reduction of nickel and molybdenum ions, followed by thermal treatment of obtained nanoparticles led to formation of core-shell structured nickel-molybdenum oxide nanoparticles. According to the results, the thickness of the s...

With the exception of nitrogenase, molybdenum is present in a diverse, but coherent group of enzymes which contain a pterin molybdenum cofactor (Moco) as a prosthetic group [l]. This group of enzymes, known as the molybdenum oxotransferases and hydroxylases, carry out a two-electron oxidation-reduction reaction which is linked to oxygen atom transfer to or from a substrate. This is illustrated ...

Three different sensitive and accurate spectroscopic procedures were developed for the determination of three angiotensin-converting enzyme inhibitors, namely, ramipril, enalapril maleate and fosinopril. The first two spectrophotometric (extractive and non-extractive) procedures were based on ternary complex formation with molybdenum(V) thiocyanate. The formed complex can be determined by extra...

A reliable method for the determination of iodine and molybdenum in milk samples, using alkaline digestion with tetramethylammonium hydroxide and hydrogen peroxide, followed by quadrupole ICP-MS analysis, has been developed and tested using certified reference materials. The use of He+O2 (1.0 ml min(-1) and 0.6 ml min(-1)) in the collision-reaction cell of the mass spectrometer to remove (129)X...

Bioleaching processes for extraction of Cu and Mo from molybdenite cons. are more environmentally friendly and consume less energy than conventional technologies, yet less economically efficient. One necessary step towards arriving at a cost-effective bioleaching process is using appropriate methodology to optimize pertinent factors in such processes. To this end, the present study employed Res...