نتایج جستجو برای: mono substituted benzene
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The title compound, C(25)H(26)N(2)O(4), exists in an E conformation with respect to each azomethine link. The two phenol-substituted benzene rings are twisted away from the plane of the diimine benzene ring by dihedral angles of 27.25 (5) and 56.67 (5)°. The mol-ecular structure is stabilized by intra-molecular O-H⋯N hydrogen bonds.
In the title mol-ecule, C(17)H(11)Cl(2)N(3)O, the C=C bond connecting the triazole and 4-chloro-phenyl groups adopts a Z geometry. The dihedral angles formed by the triazole ring and the 4-chloro substituted benzene rings are 67.3 (1) and 59.1 (1)°. The dihedral angle between the two benzene rings is 73.5 (1)°.
Substituted 1,4-diaza-1,3-butadienes with 2 equivalents of 1,4-naphthoquinone in presence of ethanol or benzene produce corresponding substituted bisindoletetrones via criss-cross cycloaddition reaction. The chemical structure was confirmed by elemental and spectral analysis. Biological activity against some micro-organisms was tested.
In the structure of the title compound, C(24)H(23)Br, the configuration about the double bond is E. The dihedral angles between the tert-butyl-substituted benzene ring and the unsubstituted and Br-substituted rings are 57.1 (2) and 78.2 (2)°, respectively. The methyl groups are disordered over two positions; the site occupancy factors are ca 0.8 and 0.2.
The title compound, C(18)H(7)BrCl(2)F(3)N(5)O(2), is an L-shaped tricyclic imine. The pyrazole ring is essentially coplanar with the nitro-substituted benzene ring [dihedral angle = 3.6 (2)°] and approximately perpendicular to the trifluoro-methyl-substituted ring [dihedral angle = 88.5 (2)°].
The title compound, C(12)H(8)N(2)O(5), was obtained by the reaction of 1-chloro-2,4-dinitro-benzene and phenol in the presence of potassium carbonate. The nitro-substituted benzene ring lies on a mirror plane, with one NO(2) group in the same plane and the other disordered across this plane. The phenoxy-benzene unit is placed perpendicular to this mirror, resulting in an exact orthogonal relati...
The asymmetric unit of the title compound, C(20)H(12)Cl(4)N(2)O(2), contains one half-mol-ecule with a center of symmetry along a C⋯C axis of the central benzene ring. The two C=O groups adopt an anti orientation and the two amide groups are twisted away from the central benzene ring by 27.38 (3) and 27.62 (4)°. The mean planes of the dichloro-substituted benzene rings are twisted by 7.95 (4)° ...
The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis-(phenyl-ethyn-yl)benzene substituted by four meth-oxy groups on the terminal benzene rings. The mol-ecule is almost planar with an r.m.s. deviation of 0.266 Å. The dihedral angles between the two terminal benzene rings and the central benzene ring are 7.96 (6) and 13.32 (7)°. In the crystal structure, mol-ecules aggregate via C-H⋯O ...
Benzene, toluene and p-xylene are derivatives of benzene, generally produced from crude petroleum and have numerous applications in industry. The aim of the present study was to evaluate the impact of biofield treatment on isotopic abundance of these benzene derivatives by gas chromatography-mass spectrometry (GC-MS). Benzene, toluene and p-xylene samples were divided into two parts: control an...
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