We report a method for obtaining highly reproducible surface-enhanced Raman spectroscopy (SERS) of single and double-stranded thiolated DNA oligomers. Following a protocol that relaxes the DNA into an extended conformation, SERS spectra of DNA oligonucleotides are found to be extremely similar, strongly dominated by the Stokes modes of adenine. A spectral correlation function analysis useful fo...

Surface-enhanced Raman spectroscopy (SERS) is considered a highly promising technology for different analytical purposes. The applications of SERS are still quite limited due its relatively poor quantitative repeatability and the fact that SERS is very sensitive to oxidation, which is a challenge especially with silver based SERS substrates. Here, the link between these phenomena is investigate...

High concentrations of bioaerosols containing bacterial, fungal and biotoxinic matter are encountered in many workplaces, e.g. solid waste treatment plants, waste water treatment plants and sewage networks. A personal bioaerosol sampler, the CIP 10-M (M-microbiologic), has been developed to measure worker exposure to airborne biological agents. This sampler is battery operated; it is light and ...

Surface-Enhanced Raman Spectroscopy (SERS) was performed to detect label-free RNA. We defined conditions which make it possible to probe the four bases of RNA, in single strands of polyadenosine (pA), polyuridine (pU), polycytosine (pC) and polyguanosine (pG). We therefore present below a quantitative analysis of mixtures of non-hybridized single strands, based on the deconvolution of the SERS ...

Several samplers (IOM, CIP 10-I v1, ACCU-CAP, and Button) were evaluated at various wood industry companies using the CALTOOL system. The results obtained show that compared to the CALTOOL mouth, which can be considered to be representative of the exposure of a person placed at the same location under the same experimental conditions, the concentrations measured by the IOM, CIP 10-I v1, and ACC...

The Gibbs sampler is the standard Markov chain Monte Carlo sampler for drawing samples from the posterior distribution of conjugate Dirichlet process mixture models. Researchers have noticed the Gibbs sampler’s tendency to get stuck in local modes and, thus, poorly explore the posterior distribution. Jain and Neal (2004) proposed a merge-split sampler in which a naive random split is sweetened ...

We design freeform lenses refracting an arbitrarily given incident field into a given fixed direction. In the near field case, we study the existence of lenses refracting a given bright object into a predefined image. We also analyze the existence of systems of mirrors that solve the near field and the far field problems for reflection.

The particle collection effi ciency of a prototype environmental tobacco smoke (ETS) sampler based on the use of thermophoresis is determined by optimizing the operational voltage that determines its thermal gradient. This sampler’s heating element was made of three sets of thermophoretic (TP) wires 25μm in diameter suspended across a channel cut in a printed circuit board and mounted with coll...

We introduce a trans-dimensional extension of the rejection sampler of von Neumann. Our interval analytic construction of the rejection sampler provides a universal method that is capable of producing exact samples from a large class of trans-dimensional target densities with locally Lipschitz arithmetical expressions. We illustrate the efficiency of the sampler by theory and by examples in up ...