Ni50Co50-layered double hydroxide/UiO-66-NH2 metal–organic framework nanocomposite (Ni50Co50-LDH/UiO-66-NH2 NC) was synthesized through a facile ultrasonic-assisted hydrothermal method. UiO-66-NH2 MOF nanocrystals were in situ grown on the surface of ultrathin 2-dimensional functionalized Ni50Co50-LDH nanosheets. Using this method, uniform architecture obtained by uniformly distributing Ni50Co5...

In this study, a TiO2/polyurethane composite (PU-TiO2) for photodegradation of formaldehyde was prepared based on TiO2 amino-functionalized with 3-aminopropyltriethoxysilane (APTS). FTIR, XPS, TG and TEM measurements demonstrated the successful amino-functionalization by APTS. Then NH2-TiO2 were incorporated into polyurethane (PU) through urea linkages, thermal stability, mechanical properties ...

High CO2 concentration in atmosphere causes serious environmental issues, and carbon capture storage technologies have attracted attention as a means to reduce the atmospheric concentration. Metal-organic frameworks (MOFs) can potentially be used for adsorption, but their poor stability microporosity limit applications. Herein, novel strategy was proposed combine cellulose aerogel hierarchicall...

Antiperovskite structure compounds (X3AB, where X is an alkali cation and A B are anions) have the potential for highly correlated motion between a cluster anion on or site. This so-called “paddle-wheel” mechanism may be basis enhanced mobility in solid electrolytes. Through combined experiments modeling, first instance of double paddle-wheel mechanism, leading to fast sodium ion conduction ant...

The hemoglobin variant South Florida has been shown by protein sequencing and fast-atom-bombardment mass spectroscopy to have a substitution of methionine for the NH2-terminal valine of the beta-globin chain. In addition, there was complete retention of the initiator methionine on the mutant polypeptide. Approximately 20% of the protein was acetylated at the NH2 terminus of the beta chain. A se...

OBJECTIVES An experimental study was performed to evaluate both in vitro and in vivo the kind of interaction between the Laur-CKK-NH2 dimer and daptomycin using two Enterococcus faecalis strains with different patterns of susceptibilities. METHODS We evaluated whether selection for daptomycin-resistant E. faecalis could be prevented in vitro by combining daptomycin with the Laur-CKK-NH2 dimer...

Immobilization of enzymes is one of the most promising methods in enzyme performance enhancement, including stability, recovery, and reusability. However, investigation of suitable solid support in enzyme immobilization is still a scientific challenge. Polyethersulfone (PES) and aminated PES (PES-NH2) were successfully synthesized as novel materials for immobilization. Membranes with various po...

An efficient nongassing electro-osmotic pump (EOP) with long-lasting electrodes and exceptionally stable operation is developed by using novel flow-through polyaniline (PANI)-wrapped aminated graphene (NH2-G) electrodes. The NH2-G/PANI electrode combines the excellent oxidation/reduction capacity of PANI with the exceptional conductivity and inertness of NH2-G. The flow rate varies linearly wit...

Mixed matrix membranes containing metal-organic frameworks have attracted large attention owing to the combined advantages of high separation performance and easy processability. In this work, CO2-philic zirconium metal organic framework UiO-66 and UiO-66-NH2 nanocrystals were synthesized and embedded into polyether block amide (PEBA) polymer membranes for CO2 separation. It can be found that a...

Lecithin:retinol acyltransferase (LRAT) catalyzes the transfer of an acyl group from the sn-1 position of phosphatidylcholine to all-trans-retinol (vitamin A) and plays an essential role in the regeneration of visual chromophore as well as in the metabolism of vitamin A. Here we demonstrate that retinylamine (Ret-NH2), a potent and selective inhibitor of 11-cis-retinal biosynthesis (Golczak, M....