In this research, tribological behavior of Ti-Ni-P intermetallic coatings on titanium substrates have been investigated under dry reciprocating conditions. Hardness profile testing results exhibit that high surface hardness has been attained and static indentation result shows that the intermetallic coating has better adhesion strength than the conventional ceramic coatings. In this respect, th...

Intermetallide phase formation was studied in a powdered Fe–Al system under layer by layer laser cladding with the aim of fabricating the gradient of properties by means of changing the Fe–Al concentration ratio in the powder mixture from layer to layer. The relationships between the laser cladding parameters and the intermetallic phase structures in the consecutively cladded layers were determ...

Intermetallic compounds containing transition metals and sp elements often form a gap at the Fermi energy due to hybridization. This gap can be exploited for applications, making these compounds the subject of intense study. For example, intermetallic semiconductors are attractive for use in thermoelectric devices due to their typically small gaps and large Seebeck coefficients (ex. ZrNiSn) [1]...

Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids [Ln(ReCp(2))(3)] (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals ...

New Mg-3Zn-2Ca magnesium alloy was prepared using different processing techniques: gravity casting as well as squeeze casting in liquid and semisolid states. Materials were further thermally treated; thermal treatment of the gravity cast alloy was additionally combined with the equal channel angular pressing (ECAP). Alloy processed by the squeeze casting in liquid as well as in semisolid state ...

The chemical pathways leading to L12 nucleation from nondilute Ni-5.2 Al-14.2 Cr at. %, fcc , at 873 K are followed with radial distribution functions and isoconcentration surface analyses of direct-space atom-probe tomographic images. Although Cr atoms initially are randomly distributed, a distribution of congruent Ni3Al short-range-order domains SRO , R 0.6 nm, results from Al diffusion durin...

Scanning tunneling microscopy (STM) has been used to investigate the nucleation and stability of iron clusters on the Al2O3/ Ni3Al(111) surface as a function of coverage and annealing temperature. We show that atomic beam deposition of iron leads to hexagonally ordered cluster arrangements with a distance of 24 Å between the clusters evidencing the template effect of the alumina film. The shape...