Abstract Hydrotalcite catalysts derived from NiAl and NiAlMg mixed oxides were successfully prepared by coprecipitation at a constant pH of 11. Physicochemical methods investigated to determine their structural textural properties. Using isopropanol as probe molecule, the acid–base properties investigated, evaluation reactivity, selectivity lifetime was established.

Nickel-rich NiAl foams, consisting of open cells with hollow struts and exhibiting two relative densities (5.0 and 6.6 pct) and average cell sizes (1.27 and 0.85 mm), were creep tested between 800 °C and 1100 °C under compressive stresses between 0.10 and 1.50 MPa. For stresses lower than 0.50 MPa, the foams exhibit secondary creep with power-law behavior characterized by creep exponents and ac...

The uniaxial compression-creep behavior of unidirectionally reinforced continuous-fiber composite materials was investigated for the case where both the matrix and the fiber underwent plastic deformation by creep. The creep behavior of NiAl composites reinforced with 5 to 20 vol pct tungsten fibers was characterized at 1025 8C. The NiAl-W composites exhibited a three-stage creep behavior, with ...

Using STM topographic imaging and spectroscopy, we have investigated the adsorption of two thioether molecules, 1,2-bis(phenylthio)benzene and (bis(3-phenylthio)-phenyl)sulfane, on noble and transition metal surfaces. The two substrates show nearly antipodal behaviour. Whereas complexes with one or two protruding centres are observed on Au(111), only flat and uniform ad-structures are found on ...

A 0.5 μm thick layer of rhodium was deposited on the CMSX 4 superalloy by the electroplating method. The rhodium-coated superalloy was hafnized and aluminized or only aluminized using the Chemical vapour deposition method. A comparison was made of the microstructure, phase composition, and oxidation resistance of three aluminide coatings: nonmodified (a), rhodium-modified (b), and rhodiumand ha...

First-principles density functional theory calculations are performed to examine five postulated diffusion mechanisms for Ni in NiAl: next-nearest-neighbor NNN jumps, the triple defect mechanism, and three variants of the six-jump cycle. In contrast to most previous theoretical work, which employed empirical interatomic potentials, we provide a more accurate nonempirical description of the mech...

High efficient and sustainable utilization of water-based lubricant is essential for saving energy. In this paper, a kind of layered double hydroxide (LDH) nanoplatelets is synthesized and well dispersed in water due to the surface modification with oleylamine. The excellent tribological properties of the oleylamine-modified Ni-Al LDH (NiAl-LDH/OAm) nanoplatelets as water-based lubricant additi...

The thermodynamic properties of Al, Ni, NiAl, and Ni3Al were studied using the first-principles approach. The 0-K total energies are calculated using the ab initio plane wave pseudopotential method within the generalized gradient approximation. The contribution to the free energy from the lattice vibration was calculated using the phonon densities of states derived by means of the ab initio lin...