This paper proposes a thermodynamical pseudo Hamiltonian formulation of Continuous Stirred Tank Reactor model in which takes place some chemical reaction. This is done both in the isothermal and non isothermal cases. It is shown that the Gibbs free energy and the opposite of entropy can be chosen as Hamiltonian function respectively. For the non isothermal case, the so called Interconnection an...

This paper suggests approaches to simulate scaling effects of thermal emission from non-isothermal pixels with a typical three-dimensional structure. We simulate effective emissivities of various V-shaped valleys by using our Monte Carlo method under the isothermal assumption. An analytical formula of the effective emissivities is derived based on photon rebounding between surfaces in the valle...

Many models simulating the behavior of Shape Memory Alloys (SMA) exist nowadays, in the one or three dimensional situation. In most of the cases they are not able to describe the non isothermal behavior of SMA due to the thermomechanical loadings. Indeed, the influence of the stress on the product phase leads to an orientation of the variants, when the temperature creates a self-accomodating ma...

A detailed kinetic study of hydroxymethylfurfural, lactulose and furosine formation was performed upon heating milk at temperatures between 90 degrees C and 140 degrees C. In case of prolonged heating, formation kinetics could be described by a fractional conversion model. Considering only the first phase of the model, kinetics could be simplified to a pseudo-zero order model. A first assessmen...

Medical-profession-accepted and the US Food and Drug Administration (FDA)-approved biodegradable polymers have been used for tissue engineering applications over the last two decades due to their good biocompatibility and acceptable biodegradation properties. Poly(L-lactide) (PLLA) is a linear aliphatic biodegradable polymer and has been widely studied for use as a scaffolding material for huma...

Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process. Because the heat effects associated with adsorption are comparatively large, the assumption of isothermal behavior is a valid approximation only when uptake rates are relatively slow. In this article, we propose to determine when it is needed to choose the isother...

The thermal behavior of two polymorphic forms of rifampicin was studied by DSC and TG/DTG. The thermoanalytical results clearly showed the differences between the two crystalline forms. Polymorph I was the most thermally stable form, the DSC curve showed no fusion for this species and the thermal decomposition process occurred around 245 °C. The DSC curve of polymorph II showed two consecutive ...

− The two-dimensional linear stability of creeping plane Couette and Poiseuille flow of a viscoelastic fluid with viscous heating is investigated using a Galerkin-type Chebyshev collocation approach and a non-isothermal formulation of the FENE-P constitutive model. Viscous heating is observed to have a destabilizing/stabilizing tendency for Couette/Poiseuille flow at long to moderate disturbanc...

This work aims at optimizing sludge pretreatment by non-isothermal sonication, varying frequency, US power (PUS) and intensity (IUS varied through probe size), as well as hydrostatic pressure and operation mode (continuous vs. sequential - or pulsed - process). Under non isothermal sonication sludge solubilization results from both ultrasound disintegration and thermal hydrolysis which are conv...

The thermal decomposition kinetics of melaminium bis(trichloroacetate) dihydrate (MTCA) has been studied by thermogravimetry and derivative thermogravimetry techniques using non-isothermal experiments at three different heating rates 10, 15, and 20 ◦C min−1. Non-isothermal studies of MTCA revealed that the decomposition occurs in three stages involving dehydration and decomposition. The apparen...