A simple, sensitive, and selective online pre-column derivatization high-performance liquid chromatographic method was developed and validated for the first time to determine trace levels of folic acid (FA). An oxidant cerium (IV) trihydroxyhydroperoxide packed reactor was used for pre-column oxidation and was combined by column switching with a C18 analytical column for sample enrichment and s...

Rolled, continuous stationary phases were constructed by tightly rolling and inserting a whole textile fabric into a chromatography column. This work reports the column performance, in terms of plate height, void fraction, and resolution, of 10 cellulose-based fabrics. The relation between fabric structural properties of yarn diameter, fabric count, fabric compressibility, and column performanc...

Chemical and thermal performance of crystalline silicotitanate (CST) and resorcinolformaldehyde (RF) ion exchange media were predicted for column configurations designed for installation in high level waste tanks and intended for cesium removal from radioactive waste supernates. Modeling predictions for the processing of a known Savannah River Site tank waste composition were generated. In a tw...

Capillary column plays an important role in nano-flow liquid chromatography coupled with tandem mass spectrometry for dealing with the high dynamic range and complexity of protein samples in shotgun proteome analysis. In this study, the integrated monolithic frit into the particulate capillary (IMFPC) column was prepared. By comparing the prepared IMFPC column with conventionally fritless capil...

Distillation has remained an important separation technology for the chemical process industries. In 1997 it was reported in the journal Chemical Engineering that about 95% of all worldwide separation processes use this technology. In the USA alone, some 40000 distillation columns represent a capital investment of about US $8 billion. They consume the energy equivalent of approximately 1 billio...

heavy metals due to their non biodegradability properties and can accumulate in living tissues, thus becoming concentrated throughout the food chain and can be readily absorbed into the human body. among them manganese was examined in this study as a pollutant. the aim of this study is the manganese removal from aqueous solution using a windy sand fixed bed column of sistan plain. flow rate, in...

The usability of a state of the art CFD simulation package as a tool for analyzing the fluid-dynamic performance of internals encountered in packed distillation columns, such as initial gas distributors, liquid distributors and liquid collectors is demonstrated. A 1.4 ID column hydraulics simulator was used to provide detailed experimental evidence on the gas distribution pattern imposed by var...

The aim of this study is to evaluate the biodegradation performance of phenol in a fixed biofilm developed in sand soil media. The parameters which had been studied and may influence the biodegradation were: a) the grain size of sand, b) the rate of flow, and c) the initial phenol loading. Laboratory scale of two columns with inner diameter of 5 cm was used. The first column was packed with fin...

A novel and simple capillary ion chromatographic method for the determination of iodide is reported. Separation was achieved on a laboratory-made packed capillary column (100 mm × 0.32 mm i.d.) packed with triacontyl-functionalized silica, followed by a modification with hexadimethrine bromide, where 1 mM sodium chloride-acetonitrile (95:5, v/v) was used as the eluent and UV-absorbing analyte ...