Selective formation of amorphous, nematic (N), and beta phases in poly(9,9-di-n-octyl-2,7-fluorene) (PFO) films was achieved via judicious choice of process parameters. Phase structure and film morphology were carefully examined by means of X-ray diffraction as well as electron microscopy. "Amorphous" thin films were obtained by quick evaporation of solvent. Slow solvent removal during film for...

BACKGROUND Bio-conjugated nanoparticles are important analytical tools with emerging biological and medical applications. In this context, in situ conjugation of nanoparticles with biomolecules via laser ablation in an aqueous media is a highly promising one-step method for the production of functional nanoparticles resulting in highly efficient conjugation. Increased yields are required, parti...

Polymer polydispersity, random conjugation of functional groups, and poorly understood structure-activity relationships have constantly hampered progress in the development of nucleic acid carriers. This review focuses on the synthetic concepts for the generation of precise polymers, site-specific conjugation strategies, and multifunctional conjugates for nucleic acid transport. Dendrimers, def...

The use of Optical Control for millimeter wave systems has been extended recently to frequencies well over 100 GHZ. New types of optical modulators, detectors and mixers can now be used to make novel systems for the first time operating at submillimeter wavelengths. In addition to the fabrication of the next generation of traveling wave polymer modulators and phototransistors, we have also deve...

It is often desirable to remove both wave front and polarization aberrations from an optical beam. Scalar phase conjugation, such as ordinary stimulated Brillouin scattering, can correct only for wave-front aberrations. We have developed a new geometry for Brillouin-enhanced four-wave mixing that performs vector phase conjugation to correct for both wave-front and polarization distortions. Resu...

Strain promoted cycloaddition is presented as a tool for RNA conjugation on the solid phase; RNA-cyclooctyne conjugates are prepared by cycloaddition to both azide (strain-promoted azide-alkyne cycloaddition, SPAAC) and nitrile oxide dipoles (strain-promoted nitrile oxide-alkyne cycloaddition, SPNOAC). The conjugation is compatible with 2'-OMe blocks and with 2'-O-TBDMS protection on the ribose...