It has become the new focus in the field of water treatment to deal with the difficult degradable organic pollutants using the transition metal and the transition metal ion. This paper examined a new activator of Fe in persulfate (K2S2O8) activation based on strong oxidizer of sulfate radicals (SO·-) for catalytic oxidation of phenol. Discuss the reaction time, activator dosing amount, K2S2O8 d...

We recently showed that superporous hydrogel (SPH) scaffolds promote long-term stem cell viability and cell driven mineralization when cells were seeded within the pores of pre-fabricated SPH scaffolds. The possibility of cell encapsulation within the SPH matrix during its fabrication was further explored in this study. The impact of each chemical component used in SPH fabrication and each step...

Cytochrome o can be chemically reduced by excess dithionite and oxidized by ferricyanide and ammonium persulfate. The latter reagent is colorless and allows spectral observations in the Soret region. The spectrum of the “oxygenated” form of the reduced cytochrome, which has absorption maxima at 576, 543, and 414 nm, is elicited in aerobic solution by enzymatic reduction with NADH, and when form...

Hairdressers are frequently exposed to bleaching powder containing persulfates, a group of compounds that may induce hypersensitivity in the airways. The mechanism causing this reaction is not clear. The aim of this study was to identify changes in the nasal lavage fluid proteome after challenge with potassium persulfate in hairdressers with bleaching powder-associated rhinitis. Furthermore, we...

Dicarboxylic acid ligands (malonate, succinate, and butylmalonate) stabilize 2 nm diameter IrO2 particles synthesized by hydrolysis of aqueous IrCl(6)2- solutions. Analogous monodentate (acetate) and tridentate (citrate) carboxylate ligands, as well as phosphonate and diphosphonate ligands, are less effective as stabilizers and lead to different degrees of nanoparticle aggregation, as evidenced...

This study focuses on development, characterization and validation of an artificial neural network (ANN) model for prediction of advanced oxidation of organics in water matrix. The different ANNs, based on multilayer perceptron (MLP) and radial basis function (RBF) methodologies, have been applied for modeling of the behavior of complex system; zero-valent iron activated persulfate oxidation (F...

BACKGROUND Persulfate salts are the main cause of occupational asthma (OA) in hairdressers. The aim of this study was to verify whether ammonium persulfate ((NH(4))(2)S(2)O(8), AP) is capable of triggering an asthma-like response in mice. METHODS BALB/c mice were dermally treated on days 1 and 8, with dimethylsulfoxide (DMSO), 1% AP or 5% AP (20 microl/ear). On day 15, the auricular lymph nod...