Keggin H3PW12O40 (PW12) and Wells-Dawson H6P2W18O60 (P2W18) heteropolyacids (HPAs) are photo(catalysts) for various acid-promoted redox catalytic reactions. Their activity increases if they deposited on certain supports as metal oxides or carbon materials. Although the surface area acid-base interactions of HPAs with considered key factors performance binary material, role local structure chang...

Abstract Hydrogen production from renewable sources is gaining increasing importance for application as fuel, in particular with high efficiency and low impact devices such fuel cells. In addition, the possibility to produce more sustainable hydrogen industrial also of interest fundamental processes, ammonia methanol synthesis. Catalytic processes are used most options sources. Catalysts direct...

In this study, sunlight was used for in situ preparation of gel-based various nanohybrid systems. A naturally occurring amino acid, l-phenylalanine derivative formed a hydrogel with graphene oxide (GO)/reduced graphene oxide (rGO) at physiological pH. This hydrogel was then used in the presence of silver ions and diffuse sunlight to form initially a tri-nanohybrid system consisting of six atom ...

ABSTRACT Surface-enhanced Raman spectroscopy (SERS) and tip-enhanced Raman spectroscopy (TERS) were until recently limited in their applicability to the majority of heterogeneous catalytic reactions. Recent developments begin to resolve the conflicting experimental requirements for SERS and TERS on the one hand, and heterogeneous catalysis on the other hand. This article discusses the developme...

a three-step selective photo-ionization for gd155 and gd157 isotopes by pulsed laser wasevaluated numerically. due to large thermal neutron absorption cross sections, these two isotopes innatural gadolinium are good candidates as burnable poison to control reactivity early in the fuel cycleand allow extended fuel burn up. rate equations have been used to calculate the dynamics of the isotopepop...

ticl4, ammonia, inorganic salts as raw material, nanometer composite-crystal tio2 powders were synthesized by two-step chemical method. precursors were crystallized with different phase and stable composite-crystal tio2 with anatase and rutile phase was prepared at low temperature. quantitative control of crystal phase was realized. remarkable factors including reaction ph value, reaction time,...

Titania, which exhibits superwetting under light illumination, has been widely used as an ideal material for environmental solution such as self-cleaning, water-air purification, and antifogging. There have been various studies to understand such superhydrophilic conversion. The origin of superwetting has not been clarified in a unified mechanism yet, which requires direct experimental investig...