نتایج جستجو برای: photochemical oxidation
تعداد نتایج: 126898 فیلتر نتایج به سال:
In this chapter we are concerned with the mechanisms of organic photochemical reactions. Two important features of mechanisms are the correlation of molecular structure with reactivity and the investigation and establishment of the details of the elementary steps involved in a photochemical process as *R proceeds to P. We shall be concerned with the experimental tools for characterizing the str...
Phenol and its derivatives are one of the most common contaminants in the aquatic ecosystem. Because of high toxicity of 2,4-DCP for aquatic life, resistance to biodegradation and potential for biological accumulation it is known as a priority contaminant in the aquatic environment. Advanced Oxidation Processes were successfully used for degradation of non-biodegradable contaminants that are re...
The phthalocyanines have recently been suggested as one of most effective possible sensitizers for photodynamic therapy and the blood viral inactivation. The further characterisation of the mechanism of human red blood cell lysis and membrane alterations upon photodynamic treatment in the presence of Zn-phthalocyanine was the aim of this study. It was found that there were (2.7+/-0.4).10(7) dye...
Photosynthetic bacteria contain bacteriochlorophyll (BChl) that absorbs light and delivers the resulting singlet excitation energy to photochemical reaction centers.' The reaction centers, which have been isolated in a form free of lightharvesting BChl,'-3 contain a photochemically specialized BChl which in Rhodopseudomonas spheroides is called P870 after its absorption maximum near 870 nm. Exc...
The complexes of the formula [Pd(phen)(tsa)] and [Pd(tsa)2] (where phen= 1,10-phenanthroline and tsa = dianion of thiosalicylic acid) were synthesized replacing solvent DMSO by water, in order to develop a cleaner chemical synthetic process. Photosensitivity of the synthesized complexes has been studied. A series of photochemical experiments has been performed to investigate the role of these c...
15 We analyze a photochemical smog episode to understand the oxidative capacity and radical chemistry of the polluted atmosphere in Hong Kong and the Pearl River Delta (PRD) region. A photochemical box model based on the Master Chemical Mechanism (MCM v3.2) is constrained by an intensive set of field observations to elucidate the budgets of ROX (ROX=OH+HO2+RO2) and NO3 radicals. Highly abundant...
Motor oil serves as a useful model system for atmospheric oxidation of hydrocarbon mixtures typical of anthropogenic atmospheric particulate matter, but its complexity often prevents comprehensive chemical speciation. In this work we fully characterize this formerly "unresolved complex mixture" at the molecular level using recently developed soft ionization gas chromatography techniques. Nuclea...
The redox chemistry of mononuclear and dinuclear gold(I) phosphine arylthiolate complexes was recently investigated by using electrochemical, chemical, and photochemical techniques. We now report the redox chemistry of dinuclear gold(I) phosphine complexes containing aliphatic dithiolate ligands. These molecules differ from previously studied gold(I) phosphine thiolate complexes in that they ar...
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