The crystal structure of the title compound, C(15)H(17)NO(2), contains two nearly identical but crystallographically independent molecules, each with a double bond connecting an azabicyclic ring system to a 3-methoxybenzylidene moiety. The space group is triclinic P-1. The benzene ring is twisted by 18.44 (5) and 22.35 (4) degrees with respect to the plane of the double bond connected to the az...

Eight meso-aryl calixphyrin derivatives were synthesized and their conformational equilibria and transitions studied with temperature-dependent NMR spectroscopy. On the basis of density functional computations, several conformer species could be identified and observed changes in chemical shifts explained. In some compounds, the aryl group rotation and porphyrin ring flipping could be monitored...

Antibodies are responsible for antigen recognition in vertebrate organisms. Practically any molecule can be bound by antibodies. In this work structures of 73 complexes of antibodies with small antigens were taken from PDB database and compared. The main epitope of studied ligands was an aromatic ring. Antibodies bound it with a deep cavity, lying between complementary determining regions (CDR)...

In this work, we analyze a series of o-hydroxyaryl aldehydes to discuss the interrelation between the resonance-assisted hydrogen bond (RAHB) formation and the aromaticity of the adjacent aromatic rings. As compared to the nonaromatic reference species (malonaldehyde), the studied compounds can be separated into two groups: first, the set of systems that have a stronger RAHB than that of the re...

In this note we shall investigate a topological version of the problem of Kurosh: “Is any algebraic algebra locally finite?” Kaplansky’s theorem concerning the local nilpotence of nil PI-algebras is well-known. We will prove a generalization of Kaplansky’s theorem to the class of locally compact rings. We use in the proof a theorem of A. I. Shirshov [8] concerning the height of a finitely gener...

To investigate the influence of carbon fiber (CF) surface treatment on the flexural strength and tribological properties of the short-cut CF/polyimide (PI) composites, pitch-based short-cut CF were treated by rare earth. The CF before and after treatment was examined by X-ray photoelectron spectroscopy (XPS) and by scanning electron microscopy (SEM). The flexural strength of the specimens was d...

Why are some (4n+2)pi systems aromatic, and some not? The ipsocentric approach to the calculation of the current density induced in a molecule by an external magnetic field predicts a four-electron diatropic (aromatic) ring current for (4n+2)pi carbocycles and a two-electron paratropic (antiaromatic) current for (4n)pi carbocycles. With the inclusion of an electronegativity parameter, an ipsoce...

let r be a ring,  be an endomorphism of r and mr be a -rigid module. amodule mr is called quasi-baer if the right annihilator of a principal submodule of r isgenerated by an idempotent. it is shown that an r-module mr is a quasi-baer module if andonly if m[[x]] is a quasi-baer module over the skew power series ring r[[x; ]].

Polylactide (PLA) stereocomplexes (SCs) containing amorphous block copolymers have gained enormous interest due to their unique properties and wide range of potential applications. In this work, we report the synthesis non-covalent triblock terpolymers: polystyrene–SCPLA–polyisoprene (PS–SC–PI) via stereocomplexation PS-b-PDLA with PI-b-PLLA diblock through solution-precipitation method. The we...

We present a new docking model for HERG channel blockade. Our new model suggests three key interactions such that (1) a protonated nitrogen of the channel blocker forms a hydrogen bond with the carbonyl oxygen of HERG residue T623; (2) an aromatic moiety of the channel blocker makes a pi-pi interaction with the aromatic ring of HERG residue Y652; and (3) a hydrophobic group of the channel block...