In the present work, plasma electrolytic oxidation (PEO) is creatively introduced as a novel method to fabricate multi-layered nanospheres. Titanium (Ti) was oxidized in phosphate-based electrolyte containing ZnO nanoparticles (NPs), which results formation of nanospheres on ceramic coating. The as-fabricated nanosphere amorphous with three-layered architecture. inner layer contains Zn, Ca and ...