This article describes the synthesis and characterization of a novel 'schizophrenic' diblock copolymer [poly(2-succinyloxyethyl methacrylate)-b-poly[(N-4-vinylbenzyl),N,N-diethylamine)]; PSEMA-b-PVEA] via reversible addition of fragmentation chain transfer (RAFT) polymerization technique. The chemical structures of all samples as representatives were characterized by means of Fourier transform ...

Here we report on the preparation of well defined water-soluble poly(2-methyl-2-oxazoline) and poly(2-ethyl-2-oxazoline) terminally equipped with a chelator (N,N',N'',N'''-tetraazacylododecane-1,4,7,10-tetraacetic acid (DOTA)) for radionuclide labeling. The tissue distribution and excretion of (111)In-labeled poly(2-alkyl-2-oxazoline)s were studied in mice. We found that the hydrophilic polymer...

Recent experimental studies [Z. Wu, B. Zhou, Z.B. Hu, Phys. Rev. Lett. 90 (2003) 048304] on an uncharged aqueous poly-N-isopropylacrylamide (PNIPAM) dispersion have shown that this microgel system is sensitive to temperature. This system was also experimentally found to be modeled quite well by microgel particles interacting via a hard-sphere repulsive plus an inverse power (temperature-depende...

The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon materi...

We present exact learning algorithms that learn several classes of (discrete) boxes in f0; : : : ; ` 1gn. In particular we learn: (1) The class of unions of O(log n) boxes in time poly(n; log `) (solving an open problem of [16, 12]; in [3] this class is shown to be learnable in time poly(n; `)). (2) The class of unions of disjoint boxes in time poly(n; t; log `), where t is the number of boxes....

Electron-rich aza-aromatic compounds such as indoles is structures of particular interest and importancein organic chemistry. A useful procedure for the preparation of new 3-sulfenyl indole derivatives using S-alkyl or S-arylthiophthalimides as sulfenylating agents and poly(N, N′-dibromo-N-ethyl-naphthyl-2,7-disulfonamide) as novel catalyst is described. The method represents an efficient prepa...

Poly-N-acetyllactosamines are attached to N-glycans, O-glycans, and glycolipids and serve as underlying glycans that provide functional oligosaccharides such as sialyl Lewis. Poly-N-acetyllactosaminyl repeats are synthesized by the alternate addition of b1,3-linked GlcNAc and b1,4-linked Gal by i-extension enzyme (iGnT) and a member of the b1,4-galactosyltransferase (b4GalT) gene family. In the...

For a binary integer program (IP) \(\max c^\mathsf {T}x, Ax \le b, x \in \{0,1\}^n\), where \(A \mathbb {R}^{m \times n}\) and \(c {R}^n\) have independent Gaussian entries the right-hand side \(b {R}^m\) satisfies that its negative coordinates \(\ell _2\) norm at most n/10, we prove gap between value of linear programming relaxation IP is upper bounded by \(\text {poly}(m)(\log n)^2 / n\) with...