We study the structural and dynamical mechanisms of reinforcement of a polymer nanocomposite (PNC) via coarse-grained molecular dynamics simulations. In a regime of strong polymer-filler interactions, the stress at failure of the PNC is clearly correlated to structural quantities, such as the filler loading, the surface area of the polymer-filler interface, and the network structure. Additional...

Frontal polymerization has been successfully used to synthesize poly(N-isopropylacrylamide) nanocomposite hydrogels containing graphene. The latter was directly achieved by ultrasound treatment of a dispersion of graphite inN-methylpyrrolidone. The dispersion, having the concentration of 2.21 g L , was characterized by TEM analysis and mixed with suitable amounts of N-isopropylacrylamide for th...

Dielectric properties of in-situ formed silver (Ag) incorporated carbon black (CB)/polymer composites were studied. In-situ formed Ag nanoparticles in the Ag/CB/epoxy composites increased the dielectric constant (K) value and decreased the dissipation factor (Df). The remarkably increased dielectric constant of the nanocomposite is due to the piling of charges at the extended interface of the i...

Asymmetric nanocomposite particle pairs of polystyrene and silica were prepared via one-step miniemulsion polymerization for the first time. The transmission electron microscopy images showed that these nanocomposite particle pairs were monodisperse and highly asymmetric in morphology. The key to obtaining the asymmetric nanocomposite particle pairs was the combination of miniemulsion polymeriz...

We investigated the fabrication of highly porous scaffolds made of three different materials [poly(propylene fumarate) (PPF) polymer, an ultra-short single-walled carbon nanotube (US-tube) nanocomposite, and a dodecylated US-tube (F-US-tube) nanocomposite] in order to evaluate the effects of material composition and porosity on scaffold pore structure, mechanical properties, and marrow stromal ...

Submitted for the MAR08 Meeting of The American Physical Society Self-Assembled Epitaxial Multiferroic Nanocomposite Films Prepared by Polymer-Assisted Deposition1 HONGMEI LUO, HAO YANG, EVE BAUER, T. MARK MCCLESKEY, ANTHONY K. BURRELL, QUANXI JIA, Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545 — Multiferroic materials, which show simultaneous ...

In this work we report on the synthesis and characterization of Au nanoparticles grown in the inner environment of cationic polyelectrolyte brushes. The nanocomposite synthesis relies on loading the macromolecular film with AuCl4 2 precursor ions followed by their in situ reduction to Au nanoparticles. We observed that the nanoparticles are uniform in size and are fully stabilized by the surrou...

nt matter & 2012 0.1016/j.nanoen.2 thor. Tel.: +1 216 . [email protected] Abstract Nanomaterials with quasi-zero, one and two dimensionalities, including silicon nanoparticles, carbon nanotubes, titanium oxide particles and graphene flakes, have been incorporated into the conducting polymer polyaniline to form nanocomposite materials for making flexible supercapacitor sheets. Characterization of...

The high aspect ratio of layered silicate nanoparticles is very convenient to modify the properties of the polymer, but the hydrophilic nature of silicate surfaces impedes their homogeneous dispersion in the organic polymer phase. The hydrophilic clay minerals are commonly treated with ammonium cations with long alkyl chains to improve the compatibility between the silicate layers and the polym...

The embedding of oxide nanoparticles in polymer matrices produces a greatly enhanced dielectric response by combining the high dielectric strength and low loss of suitable host polymers with the high electric polarizability of nanoparticles. The fabrication of oxide–polymer nanocomposites with well-controlled distributions of nanoparticles is, however, challenging due to the thermodynamic and k...