The substitution of selenium oxyanions in the hydroxyapatite structure was examined using multinuclear solid-state resonance spectroscopy (ssNMR). The study was supported by powder X-ray diffractometry (PXRD) and wavelength dispersion X-ray fluorescence (WD-XRF). Samples of pure hydroxyapatite (HA300) and selenate (HA300-1.2SeO4) or selenite (HA300-1.2SeO3) substituted hydroxyapatites were synt...

Hydroxyapatite (HA) is a calcium phosphate bioceramic widely used for bone grafting and augmentation purposes. The biological response of HA can be improved through chemical and microstructural modifications, as well as by manufacturing it as macroporous implants. In the present study, calcium deficient hydroxyapatite (CDHA) and Si substituted hydroxyapatite (SiHA) macroporous scaffolds have be...

With its good properties of biocompatibility and bioactivity hydroxyapatite (HA) is highly used as bone substitutes and as coatings on metallic prostheses. In order to improve the bioactive properties of HA, we have elaborated Zn2+ doped hydroxyapatite. Zn2+ ions substitute for Ca2+ cations in the HA structure and four Zn concentrations (Zn/Zn+Ca) were prepared at 0.5, 1, 2 and 5 at.%. To study...

Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and 1.2 wt%, respectively. Unique lattice expansions in ZnSiHA, silicate Fourier transform infrared peaks and changes to the hydroxyl I...

Potato starch is characterized by discernibly high content of starch-bound phosphate monoester groups, and metal cations are attached to the groups ion forces. A level divalent appears lead good viscosity stability potato ionically cross-linking esters. However, starches manufactured in factories Hokkaido, northernmost island Japan, do not show due potassium low cation content. To overcome this...

INTRODUCTION: Strontium plays important role in stimulating the growth of osteoblasts and enhancing the formation of new bone. Therefore, a strontium related compound strontium ranelate (SR) has recently been suggested for use as a daily supplement to treat osteoporosis. However, the true effect of strontium to the stability of hydroxyapatite (HAp) has not been well understood yet, such as why ...

The feasibility of soft mechanochemical synthesis was studied here for hydroxyapatite with various types substitution. It shown that this method allows obtaining hydroxyapatites substituted copper or iron cations and cosubstituted zinc silicate groups. Thermal stability the synthesized samples evaluated. found to preserve phase homogeneity material, temperature during preparation ceramic produc...