The Newman-Penrose constants of the spacetime corresponding to the development of the Brill-Lindquist initial data are calculated by making use of a particular representation of spatial infinity due to H. Friedrich. The Brill-Lindquist initial data set represents the head-on collision of two non-rotating black holes. In this case one non-zero constant is obtained. Its value is given in terms of...

Single-molecule methods have made it possible to apply force to an individual RNA molecule. Two beads are attached to the RNA; one is on a micropipette, the other is in a laser trap. The force on the RNA and the distance between the beads are measured. Force can change the equilibrium and the rate of any reaction in which the product has a different extension from the reactant. This review desc...

Tenascin, an important extracellular matrix protein, is subject to stretching force under physiological conditions and plays important roles in regulating the cell–matrix interactions. Using the recently developed single molecule force–ramp spectroscopy, we investigated the unfolding– folding kinetics of a recombinant tenascin fragment TNfnALL. Our results showed that all the 15 FnIII domains i...

Time-resolved studies of the title reactions have been carried out over the pressure range 1−100 Torr (in SF6 bath gas) and at temperatures in the range 293−600 K, using laser flash photolysis techniques to generate and monitor the silylenes, SiH2 and SiMe2. All three reactions showed evidence of pressure dependence, consistent with third-body assisted association reactions to form silirane pro...

In this paper we present integral cross sections (in the 5-220 meV collision energy range) and rate constants (in the 100-300 K range of temperature) for the F+HD reaction leading to HF+D and DF+H. The exact quantum reactive scattering calculations were carried out using the hyperquantization algorithm on an improved potential energy surface which incorporates the effects of open shell and fine...

Abstract Ion-pair (IP) states are the superexcited of neutral molecule that dissociate as a pair positive and negative ions. These generally present near ionization continuum molecule. IP can be accessed by using photoexcitation or electron collision technique. Different techniques widely used over years to study threshold (threshold production spectroscopy) dynamics (IP imaging states. However...

The hairpin ribozyme is a minimalist paradigm for studying RNA folding and function. In this enzyme, two domains dock by induced fit to form a catalytic core that mediates a specific backbone cleavage reaction. Here, we have fully dissected its reversible reaction pathway, which comprises two structural transitions (docking/undocking) and a chemistry step (cleavage/ligation), by applying a comb...