Abstract The synthesis of stable triacylgermenolates 3 a , b was achieved by using multiple silyl abstraction methodology. formation these new germenolates confirmed NMR spectroscopy and UV‐Vis measurements. Moreover, for the 2 LIFDI mass spectrometry to characterize compounds. Germenolates serve as starting point triaacylgermane 4 two octaacyldigermanes c d . acylgermanes spectroscopy, X‐ray c...