This reaction is equilibrium-limited to 95 to 97% conversion in 2 to 4 stages because the temperature must be kept above the dewpoint of sulfur. Additional processing must be provided to reduce the concentration of sulfurous compounds in the effluent to environmentally acceptable levels. When the reaction between H2S and SO2 is carried out in organic liquids at temperatures below 15OoC it is ir...

As reported previously (Kimura, T., Ting, J., and Huang, J. J. (1972) J Biol. Chem., 247, 4476-4479), adrenal iron-sulfur protein, which contains no tryptophan and 1 tyrosine residue at position 82, displays an anomalous fluorescence peak at 331 nm. The present study conclusively demonstrates that he emission originates from the tyrosine residue with no contribution to the fluorescence of t...

Mutants of rhodanese (EC 2.8.1.1) which substitute serine residues for each of the 4 cysteine residues have been studied to determine the roles of cysteines in the structure and function of the enzyme. The proteins compared in these studies were: the wild-type, C63S, C247S, C254S, C263S, C254S/C263S, and C63S/C254S/C263S. These current studies show that cysteine 247 is the only cysteine require...

The amine regenerator of acid removal unit in South Pars Gas Complex, Assalouyeh, Iran was modeled. This model was fitted to assess the large scale columns and allow application of solar thermal energy for production of low pressure steam. Heat transfer fluids including Therminol oil, sulfur, or salt melt could be applied to yield thermal energy from a solar collector and to store and transfer ...

Elemental sulfur (S(0) ) is deposited each summer onto surface ice at Borup Fiord pass on Ellesmere Island, Canada, when high concentrations of aqueous H(2) S are discharged from a supraglacial spring system. 16S rRNA gene clone libraries generated from sulfur deposits were dominated by β-Proteobacteria, particularly Ralstonia sp. Sulfur-cycling micro-organisms such as Thiomicrospira sp., and ε...